The first organoruthenium(IV) complexes containing nitrogen donor ligands by oxidative addition of allylic substrates to coordinatively unsaturated Ru(II) complexes

Hideo Kondo; Yoshitaka Yamaguchi; Hideo Nagashima

doi:10.1039/b002927k

The first organoruthenium(IV) complexes containing nitrogen donor ligands by oxidative addition of allylic substrates to coordinatively unsaturated Ru(II) complexes

Hideo Kondo, Yoshitaka Yamaguchi, Hideo Nagashima

Department of Applied Molecular Chemistry

Research output: Contribution to journal › Article › peer-review

52 Citations (Scopus)

Abstract

Oxidative addition of allylic substrates to coordinatively unsaturated ruthenium(II), (n⁵-C₅Me₅)Ru(amidinate) complexes, afford cationic ruthenium(IV) compounds, [(n⁵-C₅Me₅)Ru(amidinate)(n³-allyl)]⁺, which have been characterized by spectroscopic analysis and X-ray structure determination.

Original language	English
Pages (from-to)	1075-1076
Number of pages	2
Journal	Chemical Communications
Issue number	12
DOIs	https://doi.org/10.1039/b002927k
Publication status	Published - Jun 21 2000

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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10.1039/b002927k

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title = "The first organoruthenium(IV) complexes containing nitrogen donor ligands by oxidative addition of allylic substrates to coordinatively unsaturated Ru(II) complexes",

abstract = "Oxidative addition of allylic substrates to coordinatively unsaturated ruthenium(II), (n5-C5Me5)Ru(amidinate) complexes, afford cationic ruthenium(IV) compounds, [(n5-C5Me5)Ru(amidinate)(n3-allyl)]+, which have been characterized by spectroscopic analysis and X-ray structure determination.",

author = "Hideo Kondo and Yoshitaka Yamaguchi and Hideo Nagashima",

year = "2000",

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AU - Kondo, Hideo

AU - Yamaguchi, Yoshitaka

AU - Nagashima, Hideo

PY - 2000/6/21

Y1 - 2000/6/21

N2 - Oxidative addition of allylic substrates to coordinatively unsaturated ruthenium(II), (n5-C5Me5)Ru(amidinate) complexes, afford cationic ruthenium(IV) compounds, [(n5-C5Me5)Ru(amidinate)(n3-allyl)]+, which have been characterized by spectroscopic analysis and X-ray structure determination.

AB - Oxidative addition of allylic substrates to coordinatively unsaturated ruthenium(II), (n5-C5Me5)Ru(amidinate) complexes, afford cationic ruthenium(IV) compounds, [(n5-C5Me5)Ru(amidinate)(n3-allyl)]+, which have been characterized by spectroscopic analysis and X-ray structure determination.

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The first organoruthenium(IV) complexes containing nitrogen donor ligands by oxidative addition of allylic substrates to coordinatively unsaturated Ru(II) complexes

Abstract

All Science Journal Classification (ASJC) codes

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