The origin of changes in electrical properties of organic films fabricated at various vacuum-deposition rates

Amir Mikaeili, Toshinori Matsusima, Yu Esaki, Sahar Alasvand Yazdani, Chihaya Adachi, Ezeddin Mohajerani

Research output: Contribution to journalArticle

Abstract

We investigated the dependence of electrical properties on vacuum-deposition rate for films of N,N՛-diphenyl-N,N՛-bis(1-naphthyl)-1,1՛-biphenyl-4,4՛-diamine (α-NPD) and tris-(8-hydroxyquinoline)aluminium (Alq 3 ), hole- and electron-transport materials widely used in organic light-emitting diodes (OLEDs), respectively. Hole-only devices (HODs) of α-NPD showed an increase of hole current when α-NPD layers were fabricated at high deposition rates, while the tendency was opposite for electron-only devices (EODs) of Alq 3 . We found that the increased hole current at high deposition rates for HODs was caused by a horizontal orientation of α-NPD molecules relative to a substrate plane which facilitates hole transport through the films. On the other hand, the decreased electron current at high deposition rates for EODs could be ascribed to the increased surface roughness of Alq 3 films which decreases electron injection. Additionally, we demonstrated that long-term operational stability was enhanced for HODs fabricated at high deposition rates and operated at a constant current. Use of a high deposition rate means a reduction of deposition time which is helpful in OLED manufacturing. The improved device performance when high deposition rates were used and the detailed understanding of its origins as we demonstrated here would lead to fabrication of high-performance OLEDs at a low cost in the future.

Original languageEnglish
Pages (from-to)93-100
Number of pages8
JournalOptical Materials
Volume91
DOIs
Publication statusPublished - May 1 2019

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Vacuum deposition
vacuum deposition
Deposition rates
Electric properties
electrical properties
Organic light emitting diodes (OLED)
light emitting diodes
electrons
Electrons
horizontal orientation
Electron injection
Diamines
diamines
surface roughness
tendencies
manufacturing
Surface roughness
injection
aluminum
Aluminum

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Computer Science(all)
  • Atomic and Molecular Physics, and Optics
  • Electrical and Electronic Engineering

Cite this

The origin of changes in electrical properties of organic films fabricated at various vacuum-deposition rates. / Mikaeili, Amir; Matsusima, Toshinori; Esaki, Yu; Yazdani, Sahar Alasvand; Adachi, Chihaya; Mohajerani, Ezeddin.

In: Optical Materials, Vol. 91, 01.05.2019, p. 93-100.

Research output: Contribution to journalArticle

Mikaeili, Amir ; Matsusima, Toshinori ; Esaki, Yu ; Yazdani, Sahar Alasvand ; Adachi, Chihaya ; Mohajerani, Ezeddin. / The origin of changes in electrical properties of organic films fabricated at various vacuum-deposition rates. In: Optical Materials. 2019 ; Vol. 91. pp. 93-100.
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