The proton cryptate of hexaethylenetetramine

Yuji Miyahara, Yurika Tanaka, Kiichi Amimoto, Takamitsu Akazawa, Tsutomu Sakuragi, Haruhito Kobayashi, Kazuomi Kubota, Masahiko Suenaga, Hiroyuki Koyama, Takahiko Inazu

Research output: Contribution to journalArticlepeer-review

31 Citations (Scopus)

Abstract

The next higher homologue of hexamethylenetetramine was synthesized as the proton cryptate H+α1 · Br- (shown schematically), and its X-ray structure determined. The proton trapped by the lone pairs accumulated at the center of the T-symmetric tetraaza cage could not be exchanged or removed, even after heating for three days in 3 m NaOD.

Original languageEnglish
Pages (from-to)956-959
Number of pages4
JournalAngewandte Chemie - International Edition
Volume38
Issue number7
DOIs
Publication statusPublished - Apr 1 1999

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

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