The stereoselective construction of E- and Z-Δ-Ile from E-dehydroamino acid ester: the synthesis of the phomopsin A tripeptide side chain

Yoko Yasuno, Akito Nishimura, Yoshifumi Yasukawa, Yuma Karita, Yasufumi Ohfune, Tetsuro Shinada

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

The stereoselective synthesis of the phomopsin A tripeptide side chain was achieved by using methyl 2-(((benzyloxy)carbonyl)amino)-2-(diphenoxyphosphoryl)acetate as a common synthetic precursor for the synthesis of E-Δ-dehydroisoleucine and E-Δ-aspartate.

Original languageEnglish
Pages (from-to)1478-1481
Number of pages4
JournalChemical Communications
Volume52
Issue number7
DOIs
Publication statusPublished - Jan 25 2016
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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