Thermochemical stability of sulfur compounds in fuel cell gases related to fuel impurity poisoning

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Abstract

Since sulfur compounds are the major poisons of fuel cell systems, equilibrium concentrations of minor sulfur-based impurities in fuel cell fuels are thermochemically calculated in the temperature range between 400°C and 1000°C. As sulfur-based impurities in fuel cell gases, H2S(g), elementary sulfur, inorganic sulfur compounds, mercaptans, alkyl (di-)sulfides, thiophenes, and related compounds have been taken into account. Various types of fuels are also considered, including H2, H2,-CO, CO, CH4, biogas, liquidified petroleum gas, gasoline, kerosene, and diesel fuel. Among the 21 kinds of sulfur-based typical impurities considered, H2S(g) is the most stable sulfur-based species. COS(g) can also coexist, but even in CO-rich gases and in hydrocarbon-based fuels, COS concentration in equilibrium is one order or a few orders of magnitude lower than H2S concentration. Other sulfur compounds, such as CH4S(g) at intermediate temperatures and HS(g) and SO2(g) at high temperatures, are also expected to coexist but their concentrations are less than 1 ppb (parts per billion) assuming thermochemical equilibrium.

Original languageEnglish
Article number031212
JournalJournal of Fuel Cell Science and Technology
Volume5
Issue number3
DOIs
Publication statusPublished - Aug 1 2008

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Sulfur Compounds
Sulfur compounds
Sulfur
Fuel cells
Gases
Impurities
Carbon Monoxide
Thiophenes
Biofuels
Poisons
Biogas
Kerosene
Petroleum
Sulfides
Thiophene
Diesel fuels
Hydrocarbons
Sulfhydryl Compounds
Temperature
Gasoline

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Renewable Energy, Sustainability and the Environment
  • Energy Engineering and Power Technology
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

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title = "Thermochemical stability of sulfur compounds in fuel cell gases related to fuel impurity poisoning",
abstract = "Since sulfur compounds are the major poisons of fuel cell systems, equilibrium concentrations of minor sulfur-based impurities in fuel cell fuels are thermochemically calculated in the temperature range between 400°C and 1000°C. As sulfur-based impurities in fuel cell gases, H2S(g), elementary sulfur, inorganic sulfur compounds, mercaptans, alkyl (di-)sulfides, thiophenes, and related compounds have been taken into account. Various types of fuels are also considered, including H2, H2,-CO, CO, CH4, biogas, liquidified petroleum gas, gasoline, kerosene, and diesel fuel. Among the 21 kinds of sulfur-based typical impurities considered, H2S(g) is the most stable sulfur-based species. COS(g) can also coexist, but even in CO-rich gases and in hydrocarbon-based fuels, COS concentration in equilibrium is one order or a few orders of magnitude lower than H2S concentration. Other sulfur compounds, such as CH4S(g) at intermediate temperatures and HS(g) and SO2(g) at high temperatures, are also expected to coexist but their concentrations are less than 1 ppb (parts per billion) assuming thermochemical equilibrium.",
author = "Kazunari Sasaki",
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N2 - Since sulfur compounds are the major poisons of fuel cell systems, equilibrium concentrations of minor sulfur-based impurities in fuel cell fuels are thermochemically calculated in the temperature range between 400°C and 1000°C. As sulfur-based impurities in fuel cell gases, H2S(g), elementary sulfur, inorganic sulfur compounds, mercaptans, alkyl (di-)sulfides, thiophenes, and related compounds have been taken into account. Various types of fuels are also considered, including H2, H2,-CO, CO, CH4, biogas, liquidified petroleum gas, gasoline, kerosene, and diesel fuel. Among the 21 kinds of sulfur-based typical impurities considered, H2S(g) is the most stable sulfur-based species. COS(g) can also coexist, but even in CO-rich gases and in hydrocarbon-based fuels, COS concentration in equilibrium is one order or a few orders of magnitude lower than H2S concentration. Other sulfur compounds, such as CH4S(g) at intermediate temperatures and HS(g) and SO2(g) at high temperatures, are also expected to coexist but their concentrations are less than 1 ppb (parts per billion) assuming thermochemical equilibrium.

AB - Since sulfur compounds are the major poisons of fuel cell systems, equilibrium concentrations of minor sulfur-based impurities in fuel cell fuels are thermochemically calculated in the temperature range between 400°C and 1000°C. As sulfur-based impurities in fuel cell gases, H2S(g), elementary sulfur, inorganic sulfur compounds, mercaptans, alkyl (di-)sulfides, thiophenes, and related compounds have been taken into account. Various types of fuels are also considered, including H2, H2,-CO, CO, CH4, biogas, liquidified petroleum gas, gasoline, kerosene, and diesel fuel. Among the 21 kinds of sulfur-based typical impurities considered, H2S(g) is the most stable sulfur-based species. COS(g) can also coexist, but even in CO-rich gases and in hydrocarbon-based fuels, COS concentration in equilibrium is one order or a few orders of magnitude lower than H2S concentration. Other sulfur compounds, such as CH4S(g) at intermediate temperatures and HS(g) and SO2(g) at high temperatures, are also expected to coexist but their concentrations are less than 1 ppb (parts per billion) assuming thermochemical equilibrium.

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