TY - JOUR
T1 - Thermochromic crystals of the CT complex between N-salicylidene-2- aminopyridine and 1,3,5-trinitrobenzene
AU - Tanaka, Masashi
AU - Imai, Takayuki
AU - Goto, Takehiko
AU - Taka, Jun Ichiro
AU - Akamatsu, Mitsuhiro
AU - Kashino, Setsuo
AU - Mogi, Kouichi
PY - 1998/1/1
Y1 - 1998/1/1
N2 - N-Salicylidene-2-aminopyridine (NSAP) and 1,3,5-trinitrobenzene (TNB) form two kind of crystalline (1/2) complexes, forms I and II. The thermochromism was observed in a charge transfer complex form I, but not in form II. The thermochromism of these crystals was studied based on the temperature dependence of the X-ray analysis and the IR and visible absorption spectra together with the theoretical analysis.
AB - N-Salicylidene-2-aminopyridine (NSAP) and 1,3,5-trinitrobenzene (TNB) form two kind of crystalline (1/2) complexes, forms I and II. The thermochromism was observed in a charge transfer complex form I, but not in form II. The thermochromism of these crystals was studied based on the temperature dependence of the X-ray analysis and the IR and visible absorption spectra together with the theoretical analysis.
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U2 - 10.1246/bcsj.71.2561
DO - 10.1246/bcsj.71.2561
M3 - Article
AN - SCOPUS:0031791477
SN - 0009-2673
VL - 71
SP - 2561
EP - 2571
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 11
ER -