Thermochromic crystals of the CT complex between N-salicylidene-2- aminopyridine and 1,3,5-trinitrobenzene

Masashi Tanaka, Takayuki Imai, Takehiko Goto, Jun Ichiro Taka, Mitsuhiro Akamatsu, Setsuo Kashino, Koichi Mogi

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

N-Salicylidene-2-aminopyridine (NSAP) and 1,3,5-trinitrobenzene (TNB) form two kind of crystalline (1/2) complexes, forms I and II. The thermochromism was observed in a charge transfer complex form I, but not in form II. The thermochromism of these crystals was studied based on the temperature dependence of the X-ray analysis and the IR and visible absorption spectra together with the theoretical analysis.

Original languageEnglish
Pages (from-to)2561-2571
Number of pages11
JournalBulletin of the Chemical Society of Japan
Volume71
Issue number11
DOIs
Publication statusPublished - Jan 1 1998

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X ray analysis
Charge transfer
Absorption spectra
Crystalline materials
Crystals
Temperature
sym-trinitrobenzene
alpha-aminopyridine

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Thermochromic crystals of the CT complex between N-salicylidene-2- aminopyridine and 1,3,5-trinitrobenzene. / Tanaka, Masashi; Imai, Takayuki; Goto, Takehiko; Taka, Jun Ichiro; Akamatsu, Mitsuhiro; Kashino, Setsuo; Mogi, Koichi.

In: Bulletin of the Chemical Society of Japan, Vol. 71, No. 11, 01.01.1998, p. 2561-2571.

Research output: Contribution to journalArticle

Tanaka, Masashi ; Imai, Takayuki ; Goto, Takehiko ; Taka, Jun Ichiro ; Akamatsu, Mitsuhiro ; Kashino, Setsuo ; Mogi, Koichi. / Thermochromic crystals of the CT complex between N-salicylidene-2- aminopyridine and 1,3,5-trinitrobenzene. In: Bulletin of the Chemical Society of Japan. 1998 ; Vol. 71, No. 11. pp. 2561-2571.
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AU - Taka, Jun Ichiro

AU - Akamatsu, Mitsuhiro

AU - Kashino, Setsuo

AU - Mogi, Koichi

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