Thermochromic crystals of the CT complex between N-salicylidene-2- aminopyridine and 1,3,5-trinitrobenzene

Masashi Tanaka, Takayuki Imai, Takehiko Goto, Jun Ichiro Taka, Mitsuhiro Akamatsu, Setsuo Kashino, Kouichi Mogi

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Abstract

N-Salicylidene-2-aminopyridine (NSAP) and 1,3,5-trinitrobenzene (TNB) form two kind of crystalline (1/2) complexes, forms I and II. The thermochromism was observed in a charge transfer complex form I, but not in form II. The thermochromism of these crystals was studied based on the temperature dependence of the X-ray analysis and the IR and visible absorption spectra together with the theoretical analysis.

Original languageEnglish
Pages (from-to)2561-2571
Number of pages11
JournalBulletin of the Chemical Society of Japan
Volume71
Issue number11
DOIs
Publication statusPublished - Jan 1 1998
Externally publishedYes

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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