Thermodynamic analysis of trimethylgallium decomposition during GaN metal organic vapor phase epitaxy

Kazuki Sekiguchi, Hiroki Shirakawa, Kenta Chokawa, Masaaki Araidai, Yoshihiro Kangawa, Koichi Kakimoto, Kenji Shiraishi

Research output: Contribution to journalArticle

7 Citations (Scopus)

Abstract

We analyzed the decomposition of Ga(CH3)3 (TMG) during the metal organic vapor phase epitaxy (MOVPE) of GaN on the basis of first-principles calculations and thermodynamic analysis. We performed activation energy calculations of TMG decomposition and determined the main reaction processes of TMG during GaN MOVPE. We found that TMG reacts with the H2 carrier gas and that (CH3)2GaH is generated after the desorption of the methyl group. Next, (CH3)2GaH decomposes into (CH3)GaH2 and this decomposes into GaH3. Finally, GaH3 becomes GaH. In the MOVPE growth of GaN, TMG decomposes into GaH by the successive desorption of its methyl groups. The results presented here concur with recent highresolution mass spectroscopy results.

Original languageEnglish
Article number04FJ03
JournalJapanese Journal of Applied Physics
Volume57
Issue number4
DOIs
Publication statusPublished - Apr 1 2018

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Vapor phase epitaxy
vapor phase epitaxy
Thermodynamics
Decomposition
decomposition
thermodynamics
Desorption
Metals
desorption
metals
mass spectroscopy
Activation energy
Spectroscopy
activation energy
Gases
gases

All Science Journal Classification (ASJC) codes

  • Engineering(all)
  • Physics and Astronomy(all)

Cite this

Thermodynamic analysis of trimethylgallium decomposition during GaN metal organic vapor phase epitaxy. / Sekiguchi, Kazuki; Shirakawa, Hiroki; Chokawa, Kenta; Araidai, Masaaki; Kangawa, Yoshihiro; Kakimoto, Koichi; Shiraishi, Kenji.

In: Japanese Journal of Applied Physics, Vol. 57, No. 4, 04FJ03, 01.04.2018.

Research output: Contribution to journalArticle

Sekiguchi, Kazuki ; Shirakawa, Hiroki ; Chokawa, Kenta ; Araidai, Masaaki ; Kangawa, Yoshihiro ; Kakimoto, Koichi ; Shiraishi, Kenji. / Thermodynamic analysis of trimethylgallium decomposition during GaN metal organic vapor phase epitaxy. In: Japanese Journal of Applied Physics. 2018 ; Vol. 57, No. 4.
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AU - Araidai, Masaaki

AU - Kangawa, Yoshihiro

AU - Kakimoto, Koichi

AU - Shiraishi, Kenji

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