Thermodynamic studies on adsorption at interaces. V. Adsorption from micellar solution

Kinsi Motomura, Shin Ichiro Iwanaga, Michio Yamanaka, Makoto Aratono, Ryohei Matuura

Research output: Contribution to journalArticle

53 Citations (Scopus)

Abstract

The thermodynamic treatment of the preceding paper has been extended so as to be applied to the adsorption of ionic surfactant from its micellar solution at the water/air interface. The surface tension of dodecylammonium chloride solution has been measured as a function of temperature at concentrations around its critical micelle concentration (CMC). The derivative of surface tension with respect to temperature has been observed to change abruptly at the CMC and then decrease very slowly with increasing concentration. It has been asserted by comparing the thermodynamic relations with experimental results that the chemical potential of micelle depends only on temperature and pressure in a limited concentration range, and the derivative of the surface tension of micellar solution with respect to temperature is related directly to the entropy change associated with the adsorption of surfactant from the micellar state. The micelle has been concluded to be similar in thermodynamic behavior to the adsorbed film.

Original languageEnglish
Pages (from-to)151-157
Number of pages7
JournalJournal of Colloid And Interface Science
Volume86
Issue number1
DOIs
Publication statusPublished - Jan 1 1982

Fingerprint

Thermodynamics
micelles
Surface tension
Adsorption
thermodynamics
adsorption
Critical micelle concentration
Micelles
interfacial tension
Surface-Active Agents
Surface active agents
Derivatives
Temperature
surfactants
Chemical potential
temperature
Entropy
chlorides
Water
entropy

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Biomaterials
  • Surfaces, Coatings and Films
  • Colloid and Surface Chemistry

Cite this

Thermodynamic studies on adsorption at interaces. V. Adsorption from micellar solution. / Motomura, Kinsi; Iwanaga, Shin Ichiro; Yamanaka, Michio; Aratono, Makoto; Matuura, Ryohei.

In: Journal of Colloid And Interface Science, Vol. 86, No. 1, 01.01.1982, p. 151-157.

Research output: Contribution to journalArticle

Motomura, Kinsi ; Iwanaga, Shin Ichiro ; Yamanaka, Michio ; Aratono, Makoto ; Matuura, Ryohei. / Thermodynamic studies on adsorption at interaces. V. Adsorption from micellar solution. In: Journal of Colloid And Interface Science. 1982 ; Vol. 86, No. 1. pp. 151-157.
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