Thermodynamic study on phase transition in adsorbed film of fluoroalkanol at the hexane/water interface. 1. Pressure effect on the adsorption of 1,1,2,2-tetrahydroheptadecafluorodecanol

Takanori Takiue, Atsuro Yanata, Norihiro Ikeda, Kinsi Motomura, Makoto Aratono

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34 Citations (Scopus)

Abstract

The interfacial tension γ of hexane solution of 1,1,2,2-tetrahydroheptadecafluorodecanol (FC10OH) against water was measured as a function of pressure p and molality m1 at 298.15 K. The break points were observed on the γ vs p and γ vs m1 curves. The interfacial density Γ1 H increases and the volume change associated with the adsorption Δν decreases with increasing m1, and they change discontinuously at concentrations of the break points. By drawing the interfacial pressure π vs area A curve, it is concluded that two types of phase transitions take place from the gaseous to the expanded state and from the expanded to the condensed one in the adsorbed film of FC10OH. By examining our results by the Clapeyron type equations, the order of phase transition was considered first. The partial molar volume change associated with the adsorption of FC10OH was estimated and compared with that of 1-octadecanol (C18OH). It was found that FC10OH molecules were accompanied with the larger decrease in partial molar volume inherent in the interface than C18OH molecules when the phase transition takes place from the expanded to the condensed state in the adsorbed film. This suggests that the microscopic circumstance in the adsorbed film affects appreciably the volume change of adsorption.

Original languageEnglish
Pages (from-to)13743-13746
Number of pages4
JournalJournal of Physical Chemistry
Volume100
Issue number32
DOIs
Publication statusPublished - Aug 8 1996

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Pressure effects
Hexanes
pressure effects
Hexane
Phase transitions
Thermodynamics
Adsorption
Density (specific gravity)
thermodynamics
adsorption
Water
water
Molecules
Surface tension
curves
molecules
interfacial tension

All Science Journal Classification (ASJC) codes

  • Engineering(all)
  • Physical and Theoretical Chemistry

Cite this

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title = "Thermodynamic study on phase transition in adsorbed film of fluoroalkanol at the hexane/water interface. 1. Pressure effect on the adsorption of 1,1,2,2-tetrahydroheptadecafluorodecanol",
abstract = "The interfacial tension γ of hexane solution of 1,1,2,2-tetrahydroheptadecafluorodecanol (FC10OH) against water was measured as a function of pressure p and molality m1 at 298.15 K. The break points were observed on the γ vs p and γ vs m1 curves. The interfacial density Γ1 H increases and the volume change associated with the adsorption Δν decreases with increasing m1, and they change discontinuously at concentrations of the break points. By drawing the interfacial pressure π vs area A curve, it is concluded that two types of phase transitions take place from the gaseous to the expanded state and from the expanded to the condensed one in the adsorbed film of FC10OH. By examining our results by the Clapeyron type equations, the order of phase transition was considered first. The partial molar volume change associated with the adsorption of FC10OH was estimated and compared with that of 1-octadecanol (C18OH). It was found that FC10OH molecules were accompanied with the larger decrease in partial molar volume inherent in the interface than C18OH molecules when the phase transition takes place from the expanded to the condensed state in the adsorbed film. This suggests that the microscopic circumstance in the adsorbed film affects appreciably the volume change of adsorption.",
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T1 - Thermodynamic study on phase transition in adsorbed film of fluoroalkanol at the hexane/water interface. 1. Pressure effect on the adsorption of 1,1,2,2-tetrahydroheptadecafluorodecanol

AU - Takiue, Takanori

AU - Yanata, Atsuro

AU - Ikeda, Norihiro

AU - Motomura, Kinsi

AU - Aratono, Makoto

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AB - The interfacial tension γ of hexane solution of 1,1,2,2-tetrahydroheptadecafluorodecanol (FC10OH) against water was measured as a function of pressure p and molality m1 at 298.15 K. The break points were observed on the γ vs p and γ vs m1 curves. The interfacial density Γ1 H increases and the volume change associated with the adsorption Δν decreases with increasing m1, and they change discontinuously at concentrations of the break points. By drawing the interfacial pressure π vs area A curve, it is concluded that two types of phase transitions take place from the gaseous to the expanded state and from the expanded to the condensed one in the adsorbed film of FC10OH. By examining our results by the Clapeyron type equations, the order of phase transition was considered first. The partial molar volume change associated with the adsorption of FC10OH was estimated and compared with that of 1-octadecanol (C18OH). It was found that FC10OH molecules were accompanied with the larger decrease in partial molar volume inherent in the interface than C18OH molecules when the phase transition takes place from the expanded to the condensed state in the adsorbed film. This suggests that the microscopic circumstance in the adsorbed film affects appreciably the volume change of adsorption.

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