Thermodynamic study on the interaction of imidazolium salts and POE-type nonionic surfactant in the adsorbed film

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Abstract

The composition of the adsorbed film and the excess Gibbs energy of adsorption ĝH,E were evaluated from thermodynamic analysis of surface tensions for the 1-decyl-3-methylimidazoulium bromide (C 10mimBr)-tetraethylene glycol monooctyl ether (C8E 4) and 1-decyl-3-methyl-imidazolium tetrafluorobrorate (C 10mimBF4)-C8E4 systems, where the counter anion of imidazolium salts is different from each other. The higher miscibility of two components compared to an ideal mixing and thus negative ĝH,E were observed in the former, which comes from the ion-dipole interaction between imidazolium cation and the oxyethylene group of C8E4. On the other hand, the lower miscibility and thus positive ĝH,E were observed for the latter. Such differences were attributed to that BF4 - forms two hydrogen bonds and has stronger affinity with the cationic head group of C10mim + than Br-. This results in that the ion-dipole interaction between C8E4 and C10mim+ cation is diminished in the C10mimBF4-C8E 4 system.

Original languageEnglish
Pages (from-to)1209-1215
Number of pages7
JournalColloid and Polymer Science
Volume292
Issue number5
DOIs
Publication statusPublished - Jan 1 2014

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Nonionic surfactants
Cations
solubility
Solubility
Salts
Positive ions
surfactants
Thermodynamics
Ions
dipoles
salts
cations
thermodynamics
Glycols
Gibbs free energy
Bromides
Ether
Anions
Surface tension
affinity

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Polymers and Plastics
  • Colloid and Surface Chemistry
  • Materials Chemistry

Cite this

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title = "Thermodynamic study on the interaction of imidazolium salts and POE-type nonionic surfactant in the adsorbed film",
abstract = "The composition of the adsorbed film and the excess Gibbs energy of adsorption ĝH,E were evaluated from thermodynamic analysis of surface tensions for the 1-decyl-3-methylimidazoulium bromide (C 10mimBr)-tetraethylene glycol monooctyl ether (C8E 4) and 1-decyl-3-methyl-imidazolium tetrafluorobrorate (C 10mimBF4)-C8E4 systems, where the counter anion of imidazolium salts is different from each other. The higher miscibility of two components compared to an ideal mixing and thus negative ĝH,E were observed in the former, which comes from the ion-dipole interaction between imidazolium cation and the oxyethylene group of C8E4. On the other hand, the lower miscibility and thus positive ĝH,E were observed for the latter. Such differences were attributed to that BF4 - forms two hydrogen bonds and has stronger affinity with the cationic head group of C10mim + than Br-. This results in that the ion-dipole interaction between C8E4 and C10mim+ cation is diminished in the C10mimBF4-C8E 4 system.",
author = "Huihui Li and Yosuke Imai and Takanori Takiue and Hiroki Matsubara and Makoto Aratono",
year = "2014",
month = "1",
day = "1",
doi = "10.1007/s00396-014-3172-5",
language = "English",
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journal = "Colloid and Polymer Science",
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T1 - Thermodynamic study on the interaction of imidazolium salts and POE-type nonionic surfactant in the adsorbed film

AU - Li, Huihui

AU - Imai, Yosuke

AU - Takiue, Takanori

AU - Matsubara, Hiroki

AU - Aratono, Makoto

PY - 2014/1/1

Y1 - 2014/1/1

N2 - The composition of the adsorbed film and the excess Gibbs energy of adsorption ĝH,E were evaluated from thermodynamic analysis of surface tensions for the 1-decyl-3-methylimidazoulium bromide (C 10mimBr)-tetraethylene glycol monooctyl ether (C8E 4) and 1-decyl-3-methyl-imidazolium tetrafluorobrorate (C 10mimBF4)-C8E4 systems, where the counter anion of imidazolium salts is different from each other. The higher miscibility of two components compared to an ideal mixing and thus negative ĝH,E were observed in the former, which comes from the ion-dipole interaction between imidazolium cation and the oxyethylene group of C8E4. On the other hand, the lower miscibility and thus positive ĝH,E were observed for the latter. Such differences were attributed to that BF4 - forms two hydrogen bonds and has stronger affinity with the cationic head group of C10mim + than Br-. This results in that the ion-dipole interaction between C8E4 and C10mim+ cation is diminished in the C10mimBF4-C8E 4 system.

AB - The composition of the adsorbed film and the excess Gibbs energy of adsorption ĝH,E were evaluated from thermodynamic analysis of surface tensions for the 1-decyl-3-methylimidazoulium bromide (C 10mimBr)-tetraethylene glycol monooctyl ether (C8E 4) and 1-decyl-3-methyl-imidazolium tetrafluorobrorate (C 10mimBF4)-C8E4 systems, where the counter anion of imidazolium salts is different from each other. The higher miscibility of two components compared to an ideal mixing and thus negative ĝH,E were observed in the former, which comes from the ion-dipole interaction between imidazolium cation and the oxyethylene group of C8E4. On the other hand, the lower miscibility and thus positive ĝH,E were observed for the latter. Such differences were attributed to that BF4 - forms two hydrogen bonds and has stronger affinity with the cationic head group of C10mim + than Br-. This results in that the ion-dipole interaction between C8E4 and C10mim+ cation is diminished in the C10mimBF4-C8E 4 system.

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