Thieme Chemistry Journals Awardees - Where Are They Now? Rhodium-Catalyzed Synthesis of Unsymmetric Di(heteroaryl) Ethers Using Heteroaryl Exchange Reaction

Saori Tanii; Mieko Arisawa; Takaya Tougo; Kiyofumi Horiuchi; Masahiko Yamaguchi

doi:10.1055/s-0036-1588801

Thieme Chemistry Journals Awardees - Where Are They Now? Rhodium-Catalyzed Synthesis of Unsymmetric Di(heteroaryl) Ethers Using Heteroaryl Exchange Reaction

Saori Tanii, Mieko Arisawa, Takaya Tougo, Kiyofumi Horiuchi, Masahiko Yamaguchi

Research output: Contribution to journal › Article › peer-review

9 Citations (Scopus)

Abstract

Unsymmetric di(heteroaryl) ethers were synthesized by the rhodium-catalyzed heteroaryl exchange reaction of heteroaryl aryl ethers and heteroaryl esters at equilibrium. Diverse unsymmetric di(heteroaryl) ethers containing five- and six-membered heteroarenes were obtained. Di(heteroaryl) ethers can be synthesized starting from diaryl ethers, because heteroaryl aryl ethers are obtained by the heteroaryl exchange reaction of diaryl ethers.

Original language	English
Pages (from-to)	1601-1607
Number of pages	7
Journal	Synlett
Volume	28
Issue number	13
DOIs	https://doi.org/10.1055/s-0036-1588801
Publication status	Published - Aug 14 2017
Externally published	Yes

All Science Journal Classification (ASJC) codes

Organic Chemistry

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title = "Thieme Chemistry Journals Awardees - Where Are They Now? Rhodium-Catalyzed Synthesis of Unsymmetric Di(heteroaryl) Ethers Using Heteroaryl Exchange Reaction",

abstract = "Unsymmetric di(heteroaryl) ethers were synthesized by the rhodium-catalyzed heteroaryl exchange reaction of heteroaryl aryl ethers and heteroaryl esters at equilibrium. Diverse unsymmetric di(heteroaryl) ethers containing five- and six-membered heteroarenes were obtained. Di(heteroaryl) ethers can be synthesized starting from diaryl ethers, because heteroaryl aryl ethers are obtained by the heteroaryl exchange reaction of diaryl ethers.",

author = "Saori Tanii and Mieko Arisawa and Takaya Tougo and Kiyofumi Horiuchi and Masahiko Yamaguchi",

note = "Funding Information: This research was supported by the Platform Project for Supporting Drug Discovery and Life Science Research (Platform for Drug Discovery, Informatics, and Structural Life Science) from the Japan Agency for Medical Research and Development (AMED) and JSPS KAKENHI Grant Number JP15H00911. Publisher Copyright: {\textcopyright} 2017 Georg Thieme Verlag KG Stuttgart · New York.",

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doi = "10.1055/s-0036-1588801",

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AU - Tanii, Saori

AU - Arisawa, Mieko

AU - Tougo, Takaya

AU - Horiuchi, Kiyofumi

AU - Yamaguchi, Masahiko

N1 - Funding Information: This research was supported by the Platform Project for Supporting Drug Discovery and Life Science Research (Platform for Drug Discovery, Informatics, and Structural Life Science) from the Japan Agency for Medical Research and Development (AMED) and JSPS KAKENHI Grant Number JP15H00911. Publisher Copyright: © 2017 Georg Thieme Verlag KG Stuttgart · New York.

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N2 - Unsymmetric di(heteroaryl) ethers were synthesized by the rhodium-catalyzed heteroaryl exchange reaction of heteroaryl aryl ethers and heteroaryl esters at equilibrium. Diverse unsymmetric di(heteroaryl) ethers containing five- and six-membered heteroarenes were obtained. Di(heteroaryl) ethers can be synthesized starting from diaryl ethers, because heteroaryl aryl ethers are obtained by the heteroaryl exchange reaction of diaryl ethers.

AB - Unsymmetric di(heteroaryl) ethers were synthesized by the rhodium-catalyzed heteroaryl exchange reaction of heteroaryl aryl ethers and heteroaryl esters at equilibrium. Diverse unsymmetric di(heteroaryl) ethers containing five- and six-membered heteroarenes were obtained. Di(heteroaryl) ethers can be synthesized starting from diaryl ethers, because heteroaryl aryl ethers are obtained by the heteroaryl exchange reaction of diaryl ethers.

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Thieme Chemistry Journals Awardees - Where Are They Now? Rhodium-Catalyzed Synthesis of Unsymmetric Di(heteroaryl) Ethers Using Heteroaryl Exchange Reaction

Abstract

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