Thin silica film with a network structure as prepared by surface sol-gel transcription on the poly(styrene-b-4-vinylpyridine) polymer film

Norifumi Fujita, Hideyuki Otsuka, Atsushi Takahara, Seiji Shinkai

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Sol-gel polycondensation of tetraethyl orthosilicate (TEOS) was carried out on the cast film of poly(styrene-b-4-vinylpyridine) under basic (benzylamine), acidic (AcOH), and neutral (no catalyst) conditions. It was found that only under the acidic and neutral conditions, the phase-separated periodic structure of the copolymer is finely transcribed into the silica. This is a new, convenient method to create the thin, mosaic film from inorganic materials.

Original languageEnglish
Pages (from-to)352-353
Number of pages2
JournalChemistry Letters
Volume32
Issue number4
DOIs
Publication statusPublished - Apr 5 2003

Fingerprint

Styrene
Periodic structures
Transcription
Polycondensation
Polymer films
Silicon Dioxide
Sol-gels
Copolymers
Thin films
Catalysts
4-vinylpyridine
tetraethoxysilane
benzylamine

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Thin silica film with a network structure as prepared by surface sol-gel transcription on the poly(styrene-b-4-vinylpyridine) polymer film. / Fujita, Norifumi; Otsuka, Hideyuki; Takahara, Atsushi; Shinkai, Seiji.

In: Chemistry Letters, Vol. 32, No. 4, 05.04.2003, p. 352-353.

Research output: Contribution to journalArticle

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