Three-way-output response system by electric potential: UV-vis, CD, and fluorescence spectral changes upon electrolysis of the chiral ester of tetracyanoanthraquinodimethane

Hiroki Higuchi, Koji Ichioka, Hidetoshi Kawai, Kenshu Fujiwara, Masakazu Ohkita, Takashi Tsuji, Takanori Suzuki

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Abstract

The newly prepared tetracyanoanthraquinodimethane (TCNAQ) derivatives 1a,b with a chiral auxiliary are good electron acceptors and exhibit weak circular dichroism (CD) based on the absorption of TCNAQ. The twin-type electron acceptor 1c with two TCNAQ units shows larger ellipticity by exciton coupling. UV-vis, CD, and fluorescence spectra were changed drastically upon electrochemical reduction of 1c, which demonstrates the unprecedented three-way-output response system.

Original languageEnglish
Pages (from-to)3027-3030
Number of pages4
JournalTetrahedron Letters
Volume45
Issue number15
DOIs
Publication statusPublished - Apr 5 2004

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All Science Journal Classification (ASJC) codes

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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