Fluorescence lifetime of Coumarin 153 dispersed in ultrathin films of ARTON-F5023® was examined on the basis of Guided Wave Mode Excitation. The polymer containing dyes was spin-coated onto 150 nm thick-PVA (poly(vinyl alcohol)) film / 35 nm thick silver / glass plate system Mode-locked Ti:sapphire picosecond laser at 440 nm was introduced from the substrate side under the condition that guided wave mode (GWM) excitation was attained. Fluorescence from dyes in the film was detected as a function of time using a streak camera. Once the film became thinner than 100 nm, fluorescence lifetime increased with decreasing thickness, measuring that molecular motion in ultrathin films was depressed in comparison with that in the bulk. This might be because an interfacial effect between ARTON-F5023® and PVA films became dominant over the surface effect, which activates molecular motion. More conclusive discussion will be presented in a poster.
|Number of pages||1|
|Publication status||Published - Oct 18 2006|
|Event||55th SPSJ Annual Meeting - Nagoya, Japan|
Duration: May 24 2006 → May 26 2006
|Other||55th SPSJ Annual Meeting|
|Period||5/24/06 → 5/26/06|
All Science Journal Classification (ASJC) codes