Time-resolved small-angle neutron scattering study on soap-free emulsion polymerization

Ryuhei Motokawa; Satoshi Koizumi; Takeji Hashimoto; Takayuki Nakahira; Masahiko Annaka

doi:10.1016/j.physb.2006.06.082

Time-resolved small-angle neutron scattering study on soap-free emulsion polymerization

Ryuhei Motokawa, Satoshi Koizumi, Takeji Hashimoto, Takayuki Nakahira, Masahiko Annaka

Physical Chemistry

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

We investigated an aqueous soap-free emulsion polymerization process of Poly(N-isopropylacrylamide)-block-poly(ethylene glycol) by ultra-small-angle and time-resolved small-angle neutron scattering methods. The results indicate that the compartmentalization of chain end radicals into solid-like micelle cores crucially leads to the quasi-living behavior of the radical polymerization by prohibiting recombination process.

Original language	English
Pages (from-to)	780-782
Number of pages	3
Journal	Physica B: Condensed Matter
Volume	385-386 I
DOIs	https://doi.org/10.1016/j.physb.2006.06.082
Publication status	Published - Nov 27 2006

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Electrical and Electronic Engineering

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10.1016/j.physb.2006.06.082

Cite this

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title = "Time-resolved small-angle neutron scattering study on soap-free emulsion polymerization",

abstract = "We investigated an aqueous soap-free emulsion polymerization process of Poly(N-isopropylacrylamide)-block-poly(ethylene glycol) by ultra-small-angle and time-resolved small-angle neutron scattering methods. The results indicate that the compartmentalization of chain end radicals into solid-like micelle cores crucially leads to the quasi-living behavior of the radical polymerization by prohibiting recombination process.",

author = "Ryuhei Motokawa and Satoshi Koizumi and Takeji Hashimoto and Takayuki Nakahira and Masahiko Annaka",

year = "2006",

month = nov,

day = "27",

doi = "10.1016/j.physb.2006.06.082",

language = "English",

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journal = "Physica B: Condensed Matter",

issn = "0921-4526",

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T1 - Time-resolved small-angle neutron scattering study on soap-free emulsion polymerization

AU - Motokawa, Ryuhei

AU - Koizumi, Satoshi

AU - Hashimoto, Takeji

AU - Nakahira, Takayuki

AU - Annaka, Masahiko

PY - 2006/11/27

Y1 - 2006/11/27

N2 - We investigated an aqueous soap-free emulsion polymerization process of Poly(N-isopropylacrylamide)-block-poly(ethylene glycol) by ultra-small-angle and time-resolved small-angle neutron scattering methods. The results indicate that the compartmentalization of chain end radicals into solid-like micelle cores crucially leads to the quasi-living behavior of the radical polymerization by prohibiting recombination process.

AB - We investigated an aqueous soap-free emulsion polymerization process of Poly(N-isopropylacrylamide)-block-poly(ethylene glycol) by ultra-small-angle and time-resolved small-angle neutron scattering methods. The results indicate that the compartmentalization of chain end radicals into solid-like micelle cores crucially leads to the quasi-living behavior of the radical polymerization by prohibiting recombination process.

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M3 - Article

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SN - 0921-4526

VL - 385-386 I

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EP - 782

JO - Physica B: Condensed Matter

JF - Physica B: Condensed Matter

ER -

Time-resolved small-angle neutron scattering study on soap-free emulsion polymerization

Abstract

All Science Journal Classification (ASJC) codes

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