Toward advanced functional systems: Honeycomb-like polymeric surfaces incorporating polyoxovanadates with surface-appended copper-cyclam complexes

Leire Ruiz-Rubio, Beñat Artetxe, Leyre Pérez-Álvarez, Jagoba Martín-Caballero, Tatsumi Ishihara, Juan M. Gutiérrez-Zorrilla, José Luis Vilas-Vilela

Research output: Contribution to journalArticle

Abstract

In this work the immobilization of hybrid polyoxometalates (POMs) onto functional polymeric surfaces is exposed and discussed. Thus, various hybrid polymer-inorganic films were prepared by anchoring selected hybrid POMs onto tailored polymeric surfaces that consisted of breath figures (BFs) made of polystyrene-b-poly(acrylic acid)/polystyrene (PS-b-PAA/PS) blends. Functionalization of the BF films was performed by selective arrangement of acrylic acid groups of the amphiphilic block copolymer on the surface pores because of their affinition for the water condensed during breath figure formation. These carboxylic acid functional groups contained within the PAA blocks were then employed to anchor [Cu(cyclam)][{Cu(cyclam)}2(V10O28)]·10H2O (1-CuV10) and [{Cu(cyclam)}(VO3)2]·5H2O (1-CuV1), hybrid POMs by immersing the films into aqueous solutions of the in situ formed hybrid clusters, resulting in the hybrid films BF1 and BF2, respectively. Superficial analysis of these hybrid polymeric films was carried out by the sophisticated ion beam-based technique time-of-flight secondary ion mass spectrometry (ToF-SIMS) that was revealed to be an excellent method for the superficial compositional mapping of patterned surfaces.

Original languageEnglish
Article number2313
JournalMolecules
Volume24
Issue number12
DOIs
Publication statusPublished - Jan 1 2019

Fingerprint

Copper
copper
carbopol 940
Polystyrenes
acrylic acid
polystyrene
Inorganic polymers
polymeric films
Secondary ion mass spectrometry
Carboxylic Acids
block copolymers
Anchors
immobilization
Polymer films
carboxylic acids
Secondary Ion Mass Spectrometry
Functional groups
Ion beams
secondary ion mass spectrometry
Block copolymers

All Science Journal Classification (ASJC) codes

  • Analytical Chemistry
  • Chemistry (miscellaneous)
  • Molecular Medicine
  • Pharmaceutical Science
  • Drug Discovery
  • Physical and Theoretical Chemistry
  • Organic Chemistry

Cite this

Ruiz-Rubio, L., Artetxe, B., Pérez-Álvarez, L., Martín-Caballero, J., Ishihara, T., Gutiérrez-Zorrilla, J. M., & Vilas-Vilela, J. L. (2019). Toward advanced functional systems: Honeycomb-like polymeric surfaces incorporating polyoxovanadates with surface-appended copper-cyclam complexes. Molecules, 24(12), [2313]. https://doi.org/10.3390/molecules24122313

Toward advanced functional systems : Honeycomb-like polymeric surfaces incorporating polyoxovanadates with surface-appended copper-cyclam complexes. / Ruiz-Rubio, Leire; Artetxe, Beñat; Pérez-Álvarez, Leyre; Martín-Caballero, Jagoba; Ishihara, Tatsumi; Gutiérrez-Zorrilla, Juan M.; Vilas-Vilela, José Luis.

In: Molecules, Vol. 24, No. 12, 2313, 01.01.2019.

Research output: Contribution to journalArticle

Ruiz-Rubio, L, Artetxe, B, Pérez-Álvarez, L, Martín-Caballero, J, Ishihara, T, Gutiérrez-Zorrilla, JM & Vilas-Vilela, JL 2019, 'Toward advanced functional systems: Honeycomb-like polymeric surfaces incorporating polyoxovanadates with surface-appended copper-cyclam complexes', Molecules, vol. 24, no. 12, 2313. https://doi.org/10.3390/molecules24122313
Ruiz-Rubio, Leire ; Artetxe, Beñat ; Pérez-Álvarez, Leyre ; Martín-Caballero, Jagoba ; Ishihara, Tatsumi ; Gutiérrez-Zorrilla, Juan M. ; Vilas-Vilela, José Luis. / Toward advanced functional systems : Honeycomb-like polymeric surfaces incorporating polyoxovanadates with surface-appended copper-cyclam complexes. In: Molecules. 2019 ; Vol. 24, No. 12.
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