Transesterification of various methyl esters under mild conditions catalyzed by tetranuclear zinc cluster

Takanori Iwasaki; Yusuke Maegawa; Yukiko Hayashi; Takashi Ohshima; Kazushi Mashima

doi:10.1021/jo800625v

Transesterification of various methyl esters under mild conditions catalyzed by tetranuclear zinc cluster

Takanori Iwasaki, Yusuke Maegawa, Yukiko Hayashi, Takashi Ohshima, Kazushi Mashima

Research output: Contribution to journal › Article

74 Citations (Scopus)

Abstract

(Chemical Equation Presented) A new catalytic transesterification promoted by a tetranuclear zinc cluster was developed. The mild reaction conditions enabled the reactions of various functionalized substrates to proceed in good to high yield. A large-scale reaction under solvent-free conditions proceeded with a low E-factor value (0.66), indicating the high environmental and economical advantage of the present catalysis.

Original language	English
Pages (from-to)	5147-5150
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	73
Issue number	13
DOIs	https://doi.org/10.1021/jo800625v
Publication status	Published - Jul 4 2008
Externally published	Yes

Fingerprint

All Science Journal Classification (ASJC) codes

Organic Chemistry

Cite this

Iwasaki, T., Maegawa, Y., Hayashi, Y., Ohshima, T., & Mashima, K. (2008). Transesterification of various methyl esters under mild conditions catalyzed by tetranuclear zinc cluster. Journal of Organic Chemistry, 73(13), 5147-5150. https://doi.org/10.1021/jo800625v

@article{8c0caabbdf2d4a94874d975442da5923,

title = "Transesterification of various methyl esters under mild conditions catalyzed by tetranuclear zinc cluster",

abstract = "(Chemical Equation Presented) A new catalytic transesterification promoted by a tetranuclear zinc cluster was developed. The mild reaction conditions enabled the reactions of various functionalized substrates to proceed in good to high yield. A large-scale reaction under solvent-free conditions proceeded with a low E-factor value (0.66), indicating the high environmental and economical advantage of the present catalysis.",

author = "Takanori Iwasaki and Yusuke Maegawa and Yukiko Hayashi and Takashi Ohshima and Kazushi Mashima",

year = "2008",

month = "7",

day = "4",

doi = "10.1021/jo800625v",

language = "English",

volume = "73",

pages = "5147--5150",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "13",

}

TY - JOUR

T1 - Transesterification of various methyl esters under mild conditions catalyzed by tetranuclear zinc cluster

AU - Iwasaki, Takanori

AU - Maegawa, Yusuke

AU - Hayashi, Yukiko

AU - Ohshima, Takashi

AU - Mashima, Kazushi

PY - 2008/7/4

Y1 - 2008/7/4

N2 - (Chemical Equation Presented) A new catalytic transesterification promoted by a tetranuclear zinc cluster was developed. The mild reaction conditions enabled the reactions of various functionalized substrates to proceed in good to high yield. A large-scale reaction under solvent-free conditions proceeded with a low E-factor value (0.66), indicating the high environmental and economical advantage of the present catalysis.

AB - (Chemical Equation Presented) A new catalytic transesterification promoted by a tetranuclear zinc cluster was developed. The mild reaction conditions enabled the reactions of various functionalized substrates to proceed in good to high yield. A large-scale reaction under solvent-free conditions proceeded with a low E-factor value (0.66), indicating the high environmental and economical advantage of the present catalysis.

UR - http://www.scopus.com/inward/record.url?scp=46849106528&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=46849106528&partnerID=8YFLogxK

U2 - 10.1021/jo800625v

DO - 10.1021/jo800625v

M3 - Article

C2 - 18540677

AN - SCOPUS:46849106528

VL - 73

SP - 5147

EP - 5150

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

SN - 0022-3263

IS - 13

ER -

Access to Document

10.1021/jo800625v