Transesterification of various methyl esters under mild conditions catalyzed by tetranuclear zinc cluster

Takanori Iwasaki; Yusuke Maegawa; Yukiko Hayashi; Takashi Ohshima; Kazushi Mashima

doi:10.1021/jo800625v

Transesterification of various methyl esters under mild conditions catalyzed by tetranuclear zinc cluster

Takanori Iwasaki, Yusuke Maegawa, Yukiko Hayashi, Takashi Ohshima, Kazushi Mashima

Research output: Contribution to journal › Article › peer-review

80 Citations (Scopus)

Abstract

(Chemical Equation Presented) A new catalytic transesterification promoted by a tetranuclear zinc cluster was developed. The mild reaction conditions enabled the reactions of various functionalized substrates to proceed in good to high yield. A large-scale reaction under solvent-free conditions proceeded with a low E-factor value (0.66), indicating the high environmental and economical advantage of the present catalysis.

Original language	English
Pages (from-to)	5147-5150
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	73
Issue number	13
DOIs	https://doi.org/10.1021/jo800625v
Publication status	Published - Jul 4 2008
Externally published	Yes

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1021/jo800625v

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abstract = "(Chemical Equation Presented) A new catalytic transesterification promoted by a tetranuclear zinc cluster was developed. The mild reaction conditions enabled the reactions of various functionalized substrates to proceed in good to high yield. A large-scale reaction under solvent-free conditions proceeded with a low E-factor value (0.66), indicating the high environmental and economical advantage of the present catalysis.",

author = "Takanori Iwasaki and Yusuke Maegawa and Yukiko Hayashi and Takashi Ohshima and Kazushi Mashima",

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AU - Maegawa, Yusuke

AU - Hayashi, Yukiko

AU - Ohshima, Takashi

AU - Mashima, Kazushi

PY - 2008/7/4

Y1 - 2008/7/4

N2 - (Chemical Equation Presented) A new catalytic transesterification promoted by a tetranuclear zinc cluster was developed. The mild reaction conditions enabled the reactions of various functionalized substrates to proceed in good to high yield. A large-scale reaction under solvent-free conditions proceeded with a low E-factor value (0.66), indicating the high environmental and economical advantage of the present catalysis.

AB - (Chemical Equation Presented) A new catalytic transesterification promoted by a tetranuclear zinc cluster was developed. The mild reaction conditions enabled the reactions of various functionalized substrates to proceed in good to high yield. A large-scale reaction under solvent-free conditions proceeded with a low E-factor value (0.66), indicating the high environmental and economical advantage of the present catalysis.

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