Transformation of α-substituted propanols into γ-amino alcohols through nickel-catalyzed amination on the terminal γ-carbon of propanols

Satoshi Ueno; Kazumi Usui; Ryoichi Kuwano

doi:10.1055/s-0030-1260536

Transformation of α-substituted propanols into γ-amino alcohols through nickel-catalyzed amination on the terminal γ-carbon of propanols

Satoshi Ueno, Kazumi Usui, Ryoichi Kuwano

Multidisciplinary chemistry

Research output: Contribution to journal › Article › peer-review

10 Citations (Scopus)

Abstract

A nickel-phosphine complex was found to be effective as the catalyst for the transformation of alcohols into β-enaminones, which was successively converted into γ-amino alcohols by a conventional reductant. The sequential transformation is equivalent to the carbon-nitrogen bond formation at the γ-position of saturated alcohols.

Original language	English
Pages (from-to)	1303-1307
Number of pages	5
Journal	Synlett
Issue number	9
DOIs	https://doi.org/10.1055/s-0030-1260536
Publication status	Published - 2011

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1055/s-0030-1260536

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title = "Transformation of α-substituted propanols into γ-amino alcohols through nickel-catalyzed amination on the terminal γ-carbon of propanols",

abstract = "A nickel-phosphine complex was found to be effective as the catalyst for the transformation of alcohols into β-enaminones, which was successively converted into γ-amino alcohols by a conventional reductant. The sequential transformation is equivalent to the carbon-nitrogen bond formation at the γ-position of saturated alcohols.",

author = "Satoshi Ueno and Kazumi Usui and Ryoichi Kuwano",

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doi = "10.1055/s-0030-1260536",

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AU - Ueno, Satoshi

AU - Usui, Kazumi

AU - Kuwano, Ryoichi

PY - 2011

Y1 - 2011

N2 - A nickel-phosphine complex was found to be effective as the catalyst for the transformation of alcohols into β-enaminones, which was successively converted into γ-amino alcohols by a conventional reductant. The sequential transformation is equivalent to the carbon-nitrogen bond formation at the γ-position of saturated alcohols.

AB - A nickel-phosphine complex was found to be effective as the catalyst for the transformation of alcohols into β-enaminones, which was successively converted into γ-amino alcohols by a conventional reductant. The sequential transformation is equivalent to the carbon-nitrogen bond formation at the γ-position of saturated alcohols.

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JF - Synlett

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ER -

Transformation of α-substituted propanols into γ-amino alcohols through nickel-catalyzed amination on the terminal γ-carbon of propanols

Abstract

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