Transformation of α-substituted propanols into γ-amino alcohols through nickel-catalyzed amination on the terminal γ-carbon of propanols

Satoshi Ueno; Kazumi Usui; Ryoichi Kuwano

doi:10.1055/s-0030-1260536

Transformation of α-substituted propanols into γ-amino alcohols through nickel-catalyzed amination on the terminal γ-carbon of propanols

Satoshi Ueno, Kazumi Usui, Ryoichi Kuwano

Multidisciplinary chemistry

Research output: Contribution to journal › Article

8 Citations (Scopus)

Abstract

A nickel-phosphine complex was found to be effective as the catalyst for the transformation of alcohols into β-enaminones, which was successively converted into γ-amino alcohols by a conventional reductant. The sequential transformation is equivalent to the carbon-nitrogen bond formation at the γ-position of saturated alcohols.

Original language	English
Pages (from-to)	1303-1307
Number of pages	5
Journal	Synlett
Issue number	9
DOIs	https://doi.org/10.1055/s-0030-1260536
Publication status	Published - May 30 2011

All Science Journal Classification (ASJC) codes

Organic Chemistry

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Ueno, S., Usui, K., & Kuwano, R. (2011). Transformation of α-substituted propanols into γ-amino alcohols through nickel-catalyzed amination on the terminal γ-carbon of propanols. Synlett, (9), 1303-1307. https://doi.org/10.1055/s-0030-1260536

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abstract = "A nickel-phosphine complex was found to be effective as the catalyst for the transformation of alcohols into β-enaminones, which was successively converted into γ-amino alcohols by a conventional reductant. The sequential transformation is equivalent to the carbon-nitrogen bond formation at the γ-position of saturated alcohols.",

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