TY - JOUR
T1 - Translational diffusion of transient radicals studied by the transient grating method
AU - Terazima, Masahide
AU - Okamoto, Koichi
AU - Hirota, Noboru
PY - 1995/1/1
Y1 - 1995/1/1
N2 - Diffusion coefficients (D) of various radicals created by the photoinduced hydrogen abstraction reactions from alcohols (ethanol and 2-propanol) as well as those of the parent molecules are measured by using the transient grating (TG) method. Dependence of D on the viscosity, molecular size, and temperature are investigated, and the results are interpreted in terms of microscopic aggregation of the radicals with solvents or solutes.
AB - Diffusion coefficients (D) of various radicals created by the photoinduced hydrogen abstraction reactions from alcohols (ethanol and 2-propanol) as well as those of the parent molecules are measured by using the transient grating (TG) method. Dependence of D on the viscosity, molecular size, and temperature are investigated, and the results are interpreted in terms of microscopic aggregation of the radicals with solvents or solutes.
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U2 - 10.1016/S0167-6881(06)80820-7
DO - 10.1016/S0167-6881(06)80820-7
M3 - Article
AN - SCOPUS:77957076483
VL - 83
SP - 401
EP - 404
JO - Studies in Physical and Theoretical Chemistry
JF - Studies in Physical and Theoretical Chemistry
SN - 0167-6881
IS - C
ER -