Abstract
Diffusion coefficients (D) of various radicals created by the photoinduced hydrogen abstraction reactions from alcohols (ethanol and 2-propanol) as well as those of the parent molecules are measured by using the transient grating (TG) method. Dependence of D on the viscosity, molecular size, and temperature are investigated, and the results are interpreted in terms of microscopic aggregation of the radicals with solvents or solutes.
| Original language | English |
|---|---|
| Pages (from-to) | 401-404 |
| Number of pages | 4 |
| Journal | Studies in Physical and Theoretical Chemistry |
| Volume | 83 |
| Issue number | C |
| DOIs | |
| Publication status | Published - Jan 1 1995 |
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All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
Cite this
Translational diffusion of transient radicals studied by the transient grating method. / Terazima, Masahide; Okamoto, Koichi; Hirota, Noboru.
In: Studies in Physical and Theoretical Chemistry, Vol. 83, No. C, 01.01.1995, p. 401-404.Research output: Contribution to journal › Article
}
TY - JOUR
T1 - Translational diffusion of transient radicals studied by the transient grating method
AU - Terazima, Masahide
AU - Okamoto, Koichi
AU - Hirota, Noboru
PY - 1995/1/1
Y1 - 1995/1/1
N2 - Diffusion coefficients (D) of various radicals created by the photoinduced hydrogen abstraction reactions from alcohols (ethanol and 2-propanol) as well as those of the parent molecules are measured by using the transient grating (TG) method. Dependence of D on the viscosity, molecular size, and temperature are investigated, and the results are interpreted in terms of microscopic aggregation of the radicals with solvents or solutes.
AB - Diffusion coefficients (D) of various radicals created by the photoinduced hydrogen abstraction reactions from alcohols (ethanol and 2-propanol) as well as those of the parent molecules are measured by using the transient grating (TG) method. Dependence of D on the viscosity, molecular size, and temperature are investigated, and the results are interpreted in terms of microscopic aggregation of the radicals with solvents or solutes.
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UR - http://www.scopus.com/inward/citedby.url?scp=77957076483&partnerID=8YFLogxK
U2 - 10.1016/S0167-6881(06)80820-7
DO - 10.1016/S0167-6881(06)80820-7
M3 - Article
AN - SCOPUS:77957076483
VL - 83
SP - 401
EP - 404
JO - Studies in Physical and Theoretical Chemistry
JF - Studies in Physical and Theoretical Chemistry
SN - 0167-6881
IS - C
ER -