Abstract
Diffusion coefficients (D) of various radicals created by the photoinduced hydrogen abstraction reactions from alcohols (ethanol and 2-propanol) as well as those of the parent molecules are measured by using the transient grating (TG) method. Dependence of D on the viscosity, molecular size, and temperature are investigated, and the results are interpreted in terms of microscopic aggregation of the radicals with solvents or solutes.
| Original language | English |
|---|---|
| Pages (from-to) | 401-404 |
| Number of pages | 4 |
| Journal | Studies in Physical and Theoretical Chemistry |
| Volume | 83 |
| Issue number | C |
| DOIs | |
| Publication status | Published - Jan 1 1995 |
All Science Journal Classification (ASJC) codes
- Physical and Theoretical Chemistry
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Terazima, M., Okamoto, K., & Hirota, N. (1995). Translational diffusion of transient radicals studied by the transient grating method. Studies in Physical and Theoretical Chemistry, 83(C), 401-404. https://doi.org/10.1016/S0167-6881(06)80820-7