Translational diffusion of transient radicals studied by the transient grating method

Masahide Terazima; Koichi Okamoto; Noboru Hirota

doi:10.1016/0167-7322(95)00885-3

Translational diffusion of transient radicals studied by the transient grating method

Masahide Terazima, Koichi Okamoto, Noboru Hirota

Department of Fundamental Organic Chemistry

Research output: Contribution to journal › Article › peer-review

3 Citations (Scopus)

Abstract

Diffusion coefficients (D) of various radicals created by the photoinduced hydrogen abstraction reactions from alcohols (ethanol and 2-propanol) as well as those of the parent molecules are measured by using the transient grating (TG) method. Dependence of D on the viscosity, molecular size, and temperature are investigated, and the results are interpreted in terms of microscopic aggregation of the radicals with solvent or solutes.

Original language	English
Pages (from-to)	401-404
Number of pages	4
Journal	Journal of Molecular Liquids
Volume	65-66
Issue number	C
DOIs	https://doi.org/10.1016/0167-7322(95)00885-3
Publication status	Published - Jan 1 1995

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics
Condensed Matter Physics
Spectroscopy
Physical and Theoretical Chemistry
Materials Chemistry

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10.1016/0167-7322(95)00885-3

Cite this

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title = "Translational diffusion of transient radicals studied by the transient grating method",

abstract = "Diffusion coefficients (D) of various radicals created by the photoinduced hydrogen abstraction reactions from alcohols (ethanol and 2-propanol) as well as those of the parent molecules are measured by using the transient grating (TG) method. Dependence of D on the viscosity, molecular size, and temperature are investigated, and the results are interpreted in terms of microscopic aggregation of the radicals with solvent or solutes.",

author = "Masahide Terazima and Koichi Okamoto and Noboru Hirota",

year = "1995",

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AU - Hirota, Noboru

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N2 - Diffusion coefficients (D) of various radicals created by the photoinduced hydrogen abstraction reactions from alcohols (ethanol and 2-propanol) as well as those of the parent molecules are measured by using the transient grating (TG) method. Dependence of D on the viscosity, molecular size, and temperature are investigated, and the results are interpreted in terms of microscopic aggregation of the radicals with solvent or solutes.

AB - Diffusion coefficients (D) of various radicals created by the photoinduced hydrogen abstraction reactions from alcohols (ethanol and 2-propanol) as well as those of the parent molecules are measured by using the transient grating (TG) method. Dependence of D on the viscosity, molecular size, and temperature are investigated, and the results are interpreted in terms of microscopic aggregation of the radicals with solvent or solutes.

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Translational diffusion of transient radicals studied by the transient grating method

Abstract

All Science Journal Classification (ASJC) codes

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