Transport properties of comb-type grafted and normal-type N-isopropylacrylamide hydrogel

Masahiko Annaka, Masaaki Sugiyama, Masaki Kasai, Takayuki Nakahira, Toyoaki Matsuura, Hiroko Seki, Takao Aoyagi, Teruo Okano

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

Transport properties of the comb-type grafted and normal-type N-isopropylacrylamide (NIPA) gel are investigated by gel filtration chromatography and a pulsed field gradient NMR technique with known standard probe molecules in terms of molecular weight cutoff and diffusion coefficient in and through the gels, respectively. The incorporation of NIPA grafted chains into NIPA gel makes the effective mesh size smaller and induces the additional friction between the probe molecule and gel network. One may control the maximum mesh size of the NIPA gel and thus the effective diffusivity of a probe molecule within a gel by incorporating grafted chains and by adjusting the temperature.

Original languageEnglish
Pages (from-to)7377-7383
Number of pages7
JournalLangmuir
Volume18
Issue number20
DOIs
Publication statusPublished - Oct 1 2002
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Spectroscopy
  • Electrochemistry

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