Tribological behavior of ionic polymer brushes in aqueous environment

Motoyasu Kobayashi, Masami Terada, Tatsuya Ishikawa, Atsushi Takahara

Research output: Chapter in Book/Report/Conference proceedingChapter

1 Citation (Scopus)

Abstract

The surface-tethering of polymers has become a widely used method for improving the surface physicochemical properties, such as wettability, adhesion, and friction, of solid surfaces. An assembly of polymer chains end-grafted to a solid surface at a sufficiently high graft density in a good solvent is generally referred to as a “polymer brush” [1,2]. The graft density is the number of tethered chains at the surfaces per unit area, which largely depends on the preparation process, such as “grafting-to” or “grafting-from.” Over the last decade, various types of well-defined, high-density polymer brushes have been prepared via surface-initiated controlled radical polymerization (CRP). Such brushes are grown from surface initiating sites that are immobilized on solid surfaces or substrates through covalent bonding. As a result, the brush chains are strongly anchored and are hardly detached from the substrate, even in a good solvent as well as under large shear deformation. Therefore, the polymer brushes with nanometer-scale thickness can act as an efficient lubricant in friction.

Original languageEnglish
Title of host publicationSurfactants in Tribology
PublisherCRC Press
Pages75-92
Number of pages18
Volume3
ISBN (Electronic)9781439889619
ISBN (Print)9781439889589
DOIs
Publication statusPublished - Jan 1 2013

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All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Engineering(all)
  • Materials Science(all)

Cite this

Kobayashi, M., Terada, M., Ishikawa, T., & Takahara, A. (2013). Tribological behavior of ionic polymer brushes in aqueous environment. In Surfactants in Tribology (Vol. 3, pp. 75-92). CRC Press. https://doi.org/10.1201/b13897