Trifluoromethylated thermally activated delayed fluorescence molecule as a versatile photocatalyst for electron-transfer- and energy-transfer-driven reactions

Tatsuya Morofuji; Takuma Kurokawa; Youhei Chitose; Chihaya Adachi; Naokazu Kano

doi:10.1039/d2ob02055f

Trifluoromethylated thermally activated delayed fluorescence molecule as a versatile photocatalyst for electron-transfer- and energy-transfer-driven reactions

Tatsuya Morofuji, Takuma Kurokawa, Youhei Chitose, Chihaya Adachi, Naokazu Kano

Functional Materials Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

In this study, we propose that the trifluoromethylated thermally activated delayed fluorescent molecule 4[Cz(CF₃)₂]IPN is a versatile organic photocatalyst that can be used for electron-transfer-driven reactions requiring a photocatalyst with high oxidizing power and energy-transfer-driven reactions that require an Ir photocatalyst. 4[Cz(CF₃)₂]IPN was used in radical reactions via electron transfer and dearomative cycloaddition reactions via energy transfer.

Original language	English
Pages (from-to)	9600-9603
Number of pages	4
Journal	Organic and Biomolecular Chemistry
Volume	20
Issue number	48
DOIs	https://doi.org/10.1039/d2ob02055f
Publication status	Published - Nov 16 2022

All Science Journal Classification (ASJC) codes

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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Trifluoromethylated thermally activated delayed fluorescence molecule as a versatile photocatalyst for electron-transfer- and energy-transfer-driven reactions. / Morofuji, Tatsuya; Kurokawa, Takuma; Chitose, Youhei et al.

In: Organic and Biomolecular Chemistry, Vol. 20, No. 48, 16.11.2022, p. 9600-9603.

Research output: Contribution to journal › Article › peer-review

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abstract = "In this study, we propose that the trifluoromethylated thermally activated delayed fluorescent molecule 4[Cz(CF3)2]IPN is a versatile organic photocatalyst that can be used for electron-transfer-driven reactions requiring a photocatalyst with high oxidizing power and energy-transfer-driven reactions that require an Ir photocatalyst. 4[Cz(CF3)2]IPN was used in radical reactions via electron transfer and dearomative cycloaddition reactions via energy transfer.",

author = "Tatsuya Morofuji and Takuma Kurokawa and Youhei Chitose and Chihaya Adachi and Naokazu Kano",

note = "Funding Information: This research was partially supported by the Asahi Glass Foundation. Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry.",

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AU - Morofuji, Tatsuya

AU - Kurokawa, Takuma

AU - Chitose, Youhei

AU - Adachi, Chihaya

AU - Kano, Naokazu

PY - 2022/11/16

Y1 - 2022/11/16

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Trifluoromethylated thermally activated delayed fluorescence molecule as a versatile photocatalyst for electron-transfer- and energy-transfer-driven reactions

Abstract

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