Triply methoxo-bridged tetranuclear nickel cubane complexes with salicylate esters

Sotaro Kusumoto; Fumiya Kobayashi; Ryo Ohtani; Yang Kim; Shinya Hayami; Masaaki Nakamura

doi:10.1007/s10847-018-0798-9

Triply methoxo-bridged tetranuclear nickel cubane complexes with salicylate esters

Sotaro Kusumoto, Fumiya Kobayashi, Ryo Ohtani, Yang Kim, Shinya Hayami, Masaaki Nakamura

Research output: Contribution to journal › Article › peer-review

Abstract

Two tetranuclear Ni(II) clusters, [Ni(L¹)(µ₃-OCH₃)(CH₃OH)]₄·5CH₃OH (1) and [Ni(L²)(µ₃-OCH₃)(CH₃OH)]₄ (2) (HL¹ = methyl 2-hydroxy-3-methoxybenzoate; HL² = 4-(1,1,3,3-tetramethylbutyl)phenyl salicylate) were synthesized and characterized by X-ray crystallography and magnetic properties. Both complexes have [Ni₄O₄] cubane cores assembled with four triply-bridged methoxy oxygens. The temperature-dependent magnetic susceptibilities for 1 and 2 show ferromagnetic interactions between Ni(II) ions. The best fit parameters for their magnetic behaviors are J₁ = + 9.32 cm⁻¹, J₂ = − 1.66 cm⁻¹ and g = 2.24 for 1, and J₁ = + 9.82 cm⁻¹, J₂ = − 1.98 cm⁻¹, g = 2.21 for 2, respectively.

Original language	English
Pages (from-to)	195-199
Number of pages	5
Journal	Journal of Inclusion Phenomena and Macrocyclic Chemistry
Volume	94
Issue number	3-4
DOIs	https://doi.org/10.1007/s10847-018-0798-9
Publication status	Published - Aug 15 2019
Externally published	Yes

All Science Journal Classification (ASJC) codes

Food Science
Chemistry(all)
Condensed Matter Physics

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@article{9a52c7f417b04a908d71426d899ecb63,

title = "Triply methoxo-bridged tetranuclear nickel cubane complexes with salicylate esters",

abstract = "Two tetranuclear Ni(II) clusters, [Ni(L1)(µ3-OCH3)(CH3OH)]4·5CH3OH (1) and [Ni(L2)(µ3-OCH3)(CH3OH)]4 (2) (HL1 = methyl 2-hydroxy-3-methoxybenzoate; HL2 = 4-(1,1,3,3-tetramethylbutyl)phenyl salicylate) were synthesized and characterized by X-ray crystallography and magnetic properties. Both complexes have [Ni4O4] cubane cores assembled with four triply-bridged methoxy oxygens. The temperature-dependent magnetic susceptibilities for 1 and 2 show ferromagnetic interactions between Ni(II) ions. The best fit parameters for their magnetic behaviors are J1 = + 9.32 cm−1, J2 = − 1.66 cm−1 and g = 2.24 for 1, and J1 = + 9.82 cm−1, J2 = − 1.98 cm−1, g = 2.21 for 2, respectively.",

author = "Sotaro Kusumoto and Fumiya Kobayashi and Ryo Ohtani and Yang Kim and Shinya Hayami and Masaaki Nakamura",

note = "Funding Information: This work was also supported by KAKENHI Grant-in-Aid for Scientific Research (A) JP17H01200. This work was supported by JSPS Grant-in-Aid for Young Scientists (B) JP15K17833, JSPS Grant-in-Aid for Scientific Research on Innovative Areas (Dynamical Ordering & Integrated Functions JP16H00777, Mixed Anion JP17H05485). This work was partially supported by the Cooperative Research Program of {\textquoteleft}Network Joint Research Centre for Materials and Devices{\textquoteright}. ",

year = "2019",

month = aug,

day = "15",

doi = "10.1007/s10847-018-0798-9",

language = "English",

volume = "94",

pages = "195--199",

journal = "Journal of Inclusion Phenomena and Macrocyclic Chemistry",

issn = "1388-3127",

publisher = "Kluwer Academic Publishers",

number = "3-4",

}

TY - JOUR

T1 - Triply methoxo-bridged tetranuclear nickel cubane complexes with salicylate esters

AU - Kusumoto, Sotaro

AU - Kobayashi, Fumiya

AU - Ohtani, Ryo

AU - Kim, Yang

AU - Hayami, Shinya

AU - Nakamura, Masaaki

N1 - Funding Information: This work was also supported by KAKENHI Grant-in-Aid for Scientific Research (A) JP17H01200. This work was supported by JSPS Grant-in-Aid for Young Scientists (B) JP15K17833, JSPS Grant-in-Aid for Scientific Research on Innovative Areas (Dynamical Ordering & Integrated Functions JP16H00777, Mixed Anion JP17H05485). This work was partially supported by the Cooperative Research Program of ‘Network Joint Research Centre for Materials and Devices’.

PY - 2019/8/15

Y1 - 2019/8/15

N2 - Two tetranuclear Ni(II) clusters, [Ni(L1)(µ3-OCH3)(CH3OH)]4·5CH3OH (1) and [Ni(L2)(µ3-OCH3)(CH3OH)]4 (2) (HL1 = methyl 2-hydroxy-3-methoxybenzoate; HL2 = 4-(1,1,3,3-tetramethylbutyl)phenyl salicylate) were synthesized and characterized by X-ray crystallography and magnetic properties. Both complexes have [Ni4O4] cubane cores assembled with four triply-bridged methoxy oxygens. The temperature-dependent magnetic susceptibilities for 1 and 2 show ferromagnetic interactions between Ni(II) ions. The best fit parameters for their magnetic behaviors are J1 = + 9.32 cm−1, J2 = − 1.66 cm−1 and g = 2.24 for 1, and J1 = + 9.82 cm−1, J2 = − 1.98 cm−1, g = 2.21 for 2, respectively.

AB - Two tetranuclear Ni(II) clusters, [Ni(L1)(µ3-OCH3)(CH3OH)]4·5CH3OH (1) and [Ni(L2)(µ3-OCH3)(CH3OH)]4 (2) (HL1 = methyl 2-hydroxy-3-methoxybenzoate; HL2 = 4-(1,1,3,3-tetramethylbutyl)phenyl salicylate) were synthesized and characterized by X-ray crystallography and magnetic properties. Both complexes have [Ni4O4] cubane cores assembled with four triply-bridged methoxy oxygens. The temperature-dependent magnetic susceptibilities for 1 and 2 show ferromagnetic interactions between Ni(II) ions. The best fit parameters for their magnetic behaviors are J1 = + 9.32 cm−1, J2 = − 1.66 cm−1 and g = 2.24 for 1, and J1 = + 9.82 cm−1, J2 = − 1.98 cm−1, g = 2.21 for 2, respectively.

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U2 - 10.1007/s10847-018-0798-9

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VL - 94

SP - 195

EP - 199

JO - Journal of Inclusion Phenomena and Macrocyclic Chemistry

JF - Journal of Inclusion Phenomena and Macrocyclic Chemistry

SN - 1388-3127

IS - 3-4

ER -