Triply N-confused hexaphyrins: Near-infrared luminescent dyes with a triangular shape

Yong Shu Xie, Keisuke Yamaguchi, Motoki Toganoh, Hidemitsu Uno, Masaaki Suzuki, Shigeki Mori, Shohei Saito, Atsuhiro Osuka, Hiroyuki Furuta

Research output: Contribution to journalArticle

55 Citations (Scopus)

Abstract

Getting in shape: Meso-pentafluorophenyl triply N-confused hexaphyrins have been synthesized in the free-base and oxidized forms and shown to have a triangular shape and efficient emission in the NIR region (see picture). The triangular shape is achieved by the presence of alternating confused and normal pyrrole rings. DFT calculations show that the triangular shape is more stable than a rectangular form.

Original languageEnglish
Pages (from-to)5496-5499
Number of pages4
JournalAngewandte Chemie - International Edition
Volume48
Issue number30
DOIs
Publication statusPublished - Jul 13 2009

Fingerprint

Pyrroles
Discrete Fourier transforms
Coloring Agents
Dyes
Infrared radiation

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)

Cite this

Triply N-confused hexaphyrins : Near-infrared luminescent dyes with a triangular shape. / Xie, Yong Shu; Yamaguchi, Keisuke; Toganoh, Motoki; Uno, Hidemitsu; Suzuki, Masaaki; Mori, Shigeki; Saito, Shohei; Osuka, Atsuhiro; Furuta, Hiroyuki.

In: Angewandte Chemie - International Edition, Vol. 48, No. 30, 13.07.2009, p. 5496-5499.

Research output: Contribution to journalArticle

Xie, Yong Shu ; Yamaguchi, Keisuke ; Toganoh, Motoki ; Uno, Hidemitsu ; Suzuki, Masaaki ; Mori, Shigeki ; Saito, Shohei ; Osuka, Atsuhiro ; Furuta, Hiroyuki. / Triply N-confused hexaphyrins : Near-infrared luminescent dyes with a triangular shape. In: Angewandte Chemie - International Edition. 2009 ; Vol. 48, No. 30. pp. 5496-5499.
@article{1a3fd1230c8b4f44b98d06d405f30088,
title = "Triply N-confused hexaphyrins: Near-infrared luminescent dyes with a triangular shape",
abstract = "Getting in shape: Meso-pentafluorophenyl triply N-confused hexaphyrins have been synthesized in the free-base and oxidized forms and shown to have a triangular shape and efficient emission in the NIR region (see picture). The triangular shape is achieved by the presence of alternating confused and normal pyrrole rings. DFT calculations show that the triangular shape is more stable than a rectangular form.",
author = "Xie, {Yong Shu} and Keisuke Yamaguchi and Motoki Toganoh and Hidemitsu Uno and Masaaki Suzuki and Shigeki Mori and Shohei Saito and Atsuhiro Osuka and Hiroyuki Furuta",
year = "2009",
month = "7",
day = "13",
doi = "10.1002/anie.200900596",
language = "English",
volume = "48",
pages = "5496--5499",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
publisher = "John Wiley and Sons Ltd",
number = "30",

}

TY - JOUR

T1 - Triply N-confused hexaphyrins

T2 - Near-infrared luminescent dyes with a triangular shape

AU - Xie, Yong Shu

AU - Yamaguchi, Keisuke

AU - Toganoh, Motoki

AU - Uno, Hidemitsu

AU - Suzuki, Masaaki

AU - Mori, Shigeki

AU - Saito, Shohei

AU - Osuka, Atsuhiro

AU - Furuta, Hiroyuki

PY - 2009/7/13

Y1 - 2009/7/13

N2 - Getting in shape: Meso-pentafluorophenyl triply N-confused hexaphyrins have been synthesized in the free-base and oxidized forms and shown to have a triangular shape and efficient emission in the NIR region (see picture). The triangular shape is achieved by the presence of alternating confused and normal pyrrole rings. DFT calculations show that the triangular shape is more stable than a rectangular form.

AB - Getting in shape: Meso-pentafluorophenyl triply N-confused hexaphyrins have been synthesized in the free-base and oxidized forms and shown to have a triangular shape and efficient emission in the NIR region (see picture). The triangular shape is achieved by the presence of alternating confused and normal pyrrole rings. DFT calculations show that the triangular shape is more stable than a rectangular form.

UR - http://www.scopus.com/inward/record.url?scp=70349985636&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=70349985636&partnerID=8YFLogxK

U2 - 10.1002/anie.200900596

DO - 10.1002/anie.200900596

M3 - Article

C2 - 19455535

AN - SCOPUS:70349985636

VL - 48

SP - 5496

EP - 5499

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

SN - 1433-7851

IS - 30

ER -