Tunable doping of graphene nanoribbon arrays by chemical functionalization

We demonstrate the controlled tuning of the electronic band structure of large-arrays of graphene nanoribbons (GNRs) by chemical functionalization. The GNR arrays are synthesized by substrate-controlled metal-assisted etching of graphene in H₂ at high temperature, and functionalized with different molecules. From Raman spectroscopy and carrier transport measurements, we found that 4-nitrobenzenediazonium (4-NBD) and diethylene triamine (DETA) molecules can tune the doping level of the GNR arrays to p- and n-type, respectively. In both cases, the doping effects induced in the GNRs were found to be higher than for a pristine graphene sheet, due to the presence of a large quantity of edges. Effects of chemical doping on the Raman spectrum of sp² carbon materials are also discussed. Our findings offer an effective way to control the electronic structure of GNRs by chemical functionalization, and are expected to facilitate the production of nanoribbon-based p-n junctions for future implementation into electronic circuits. This journal is