Two coordination polymers of manganese(II) isophthalate and their preparation, structures, and magnetic properties

Jinxi Chen, Jingjing Wang, Masaaki Ohba

Research output: Contribution to journalArticle

5 Citations (Scopus)

Abstract

Two manganese coordination polymers, [Mn 2(ip) 2(dmf)]·dmf (1) and [Mn 4(ip) 4(dmf) 6]·2dmf (2) (ip=isophthalate; dmf=N,N-dimethylformamide), have been synthesized and characterized. X-ray crystal structural data reveal that compound 1 crystallizes in triclinic space group P-1, a=9.716(3) Å, b=12.193(3) Å, c=12.576(3) Å, α=62.19(2)°, β=66.423(17)°, γ=72.72(2)°, Z=2, while compound 2 crystallizes in monoclinic space group Cc, a=19.80(3) Å, b=20.20(2) Å, c=18.01(3) Å, β=108.40(4)°, Z=4. Variable-temperature magnetic susceptibilities of compounds 1 and 2 exhibit overall weak antiferromagnetic coupling between the adjacent Mn(II) ions.

Original languageEnglish
Pages (from-to)37-41
Number of pages5
JournalJournal of Solid State Chemistry
Volume185
DOIs
Publication statusPublished - Jan 1 2012

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Dimethylformamide
Manganese
coordination polymers
Magnetic susceptibility
manganese
Magnetic properties
Polymers
Ions
magnetic properties
X rays
preparation
Crystals
magnetic permeability
Temperature
crystals
ions
x rays
temperature
isophthalate

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Two coordination polymers of manganese(II) isophthalate and their preparation, structures, and magnetic properties. / Chen, Jinxi; Wang, Jingjing; Ohba, Masaaki.

In: Journal of Solid State Chemistry, Vol. 185, 01.01.2012, p. 37-41.

Research output: Contribution to journalArticle

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N2 - Two manganese coordination polymers, [Mn 2(ip) 2(dmf)]·dmf (1) and [Mn 4(ip) 4(dmf) 6]·2dmf (2) (ip=isophthalate; dmf=N,N-dimethylformamide), have been synthesized and characterized. X-ray crystal structural data reveal that compound 1 crystallizes in triclinic space group P-1, a=9.716(3) Å, b=12.193(3) Å, c=12.576(3) Å, α=62.19(2)°, β=66.423(17)°, γ=72.72(2)°, Z=2, while compound 2 crystallizes in monoclinic space group Cc, a=19.80(3) Å, b=20.20(2) Å, c=18.01(3) Å, β=108.40(4)°, Z=4. Variable-temperature magnetic susceptibilities of compounds 1 and 2 exhibit overall weak antiferromagnetic coupling between the adjacent Mn(II) ions.

AB - Two manganese coordination polymers, [Mn 2(ip) 2(dmf)]·dmf (1) and [Mn 4(ip) 4(dmf) 6]·2dmf (2) (ip=isophthalate; dmf=N,N-dimethylformamide), have been synthesized and characterized. X-ray crystal structural data reveal that compound 1 crystallizes in triclinic space group P-1, a=9.716(3) Å, b=12.193(3) Å, c=12.576(3) Å, α=62.19(2)°, β=66.423(17)°, γ=72.72(2)°, Z=2, while compound 2 crystallizes in monoclinic space group Cc, a=19.80(3) Å, b=20.20(2) Å, c=18.01(3) Å, β=108.40(4)°, Z=4. Variable-temperature magnetic susceptibilities of compounds 1 and 2 exhibit overall weak antiferromagnetic coupling between the adjacent Mn(II) ions.

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