TY - JOUR
T1 - Two-Dimensional Cobalt Phosphate Hydroxide Nanosheets
T2 - A New Type of High-Performance Electrocatalysts with Intrinsic CoO6 Lattice Distortion for Water Oxidation
AU - Bu, Xiuming
AU - Chiang, Chaolung
AU - Wei, Renjie
AU - Li, Zebiao
AU - Meng, You
AU - Peng, Chunkuo
AU - Lin, Yuchang
AU - Li, Yangyang
AU - Lin, Yangu
AU - Chan, Kwok Sum
AU - Ho, Johnny C.
N1 - Funding Information:
This work is financially supported by the National Natural Science Foundation of China (Grants 51672229), the Science Technology and Innovation Committee of Shenzhen Municipality (Grant JCYJ20170818095520778), the City University of Hong Kong (Project 9610427), and a grant from the Shenzhen Research Institute, City University of Hong Kong.
Publisher Copyright:
© 2019 American Chemical Society.
PY - 2019/10/23
Y1 - 2019/10/23
N2 - Despite the recent advances in electrochemical water splitting, developing cost-effective and highly efficient electrocatalysts for oxygen evolution reaction (OER) still remains a substantial challenge. Herein, two-dimensional cobalt phosphate hydroxides (Co5(PO4)2(OH)4) nanosheets, a unique stacking-disordered phosphate-based inorganic material, are successfully prepared via a facile and scalable method for the first time to serve as a superior and robust electrocatalyst for water oxidation. On the basis of the detailed characterization (e.g., X-ray absorption near-edge structure and X-ray photoelectron spectroscopy), the obtained nanosheets consist of special zigzag CoO6 octahedral chains along with intrinsic lattice distortion and excellent hydrophilicity, in which these factors contribute to the highly efficient performance of prepared electrocatalysts for OER. Specifically, Co5(PO4)2(OH)4 deposited on glassy carbon electrode (loading amount ≈0.553 mg cm-2) can exhibit an unprecedented overpotential of 254 mV to drive a current density of 10 mA cm-2 with a small Tafel slope of 57 mV dec-1 in alkaline electrolytes, which outperforms the ones of CO3(PO4)2 (370 mV) and Co(OH)2 (360 mV) as well as other advanced catalysts. Evidently, this work has opened a new pathway to the rational design of promising metal phosphate hydroxides toward the efficient electrochemical energy conversion.
AB - Despite the recent advances in electrochemical water splitting, developing cost-effective and highly efficient electrocatalysts for oxygen evolution reaction (OER) still remains a substantial challenge. Herein, two-dimensional cobalt phosphate hydroxides (Co5(PO4)2(OH)4) nanosheets, a unique stacking-disordered phosphate-based inorganic material, are successfully prepared via a facile and scalable method for the first time to serve as a superior and robust electrocatalyst for water oxidation. On the basis of the detailed characterization (e.g., X-ray absorption near-edge structure and X-ray photoelectron spectroscopy), the obtained nanosheets consist of special zigzag CoO6 octahedral chains along with intrinsic lattice distortion and excellent hydrophilicity, in which these factors contribute to the highly efficient performance of prepared electrocatalysts for OER. Specifically, Co5(PO4)2(OH)4 deposited on glassy carbon electrode (loading amount ≈0.553 mg cm-2) can exhibit an unprecedented overpotential of 254 mV to drive a current density of 10 mA cm-2 with a small Tafel slope of 57 mV dec-1 in alkaline electrolytes, which outperforms the ones of CO3(PO4)2 (370 mV) and Co(OH)2 (360 mV) as well as other advanced catalysts. Evidently, this work has opened a new pathway to the rational design of promising metal phosphate hydroxides toward the efficient electrochemical energy conversion.
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U2 - 10.1021/acsami.9b11594
DO - 10.1021/acsami.9b11594
M3 - Article
C2 - 31550123
AN - SCOPUS:85073050977
VL - 11
SP - 38633
EP - 38640
JO - ACS applied materials & interfaces
JF - ACS applied materials & interfaces
SN - 1944-8244
IS - 42
ER -
