Two-dimensional triangular-lattice Cu(OH)Cl, belloite, as a magnetodielectric system

Xu Guang Zheng, Ichihiro Yamauchi, Shigeto Kitajima, Masayoshi Fujihala, M. Maki, Sanghyun Lee, Masato Hagihala, S. Torii, T. Kamiyama, Tatsuya Kawae

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Abstract

Quantum spins on a triangular lattice may bring out intriguing and exotic quantum ground states. Here we report a magnetodielectric system of CuOHCl wherein S=1/2Cu2+ spins constitute a two-dimensional triangular lattice with the layers weakly coupled via Cl-H-O bonding. Despite strong magnetic interactions, as expected from the relatively high value of θCW=-100K, antiferromagnetic transition occurred at TN=11K, followed by an uprising turn of the magnetic susceptibility below ∼7 K. Neutron-diffraction experiment revealed a coplanar spin structure on the triangular lattice below the TN, with each spin pointing toward the center of a triangle. Of the three spins on a triangle, two are antiparallel and the third one is angled 120 to the antiparallel spins. A concerted effect of geometric frustration in the triangular lattice and superexchange interactions through a zig-zag path via double Cu-O-Cu and double Cu-Cl-Cu bridges counted for this spin arrangement. Further investigation using dielectric constant and heat capacity measurements, as well as a microscopic probe of muon spin rotation, revealed a magnetodielectric effect and the possibility of multiferroic transition at T∗∼5K, which is suspected to be in close relation to geometric frustration in this triangular lattice. The present paper presents a magnetodielectric system on a two-dimensional triangular lattice with chemical stoichiometry. It can also serve as a rare reference to the hotly debated quantum spin-orbital liquid compound LiNiO2.

Original languageEnglish
Article number104401
JournalPhysical Review Materials
Volume2
Issue number10
DOIs
Publication statusPublished - Oct 2 2018

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Physics and Astronomy (miscellaneous)

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    Zheng, X. G., Yamauchi, I., Kitajima, S., Fujihala, M., Maki, M., Lee, S., Hagihala, M., Torii, S., Kamiyama, T., & Kawae, T. (2018). Two-dimensional triangular-lattice Cu(OH)Cl, belloite, as a magnetodielectric system. Physical Review Materials, 2(10), [104401]. https://doi.org/10.1103/PhysRevMaterials.2.104401