Two new coordination polymers based on hexanuclear metal cluster cores

Jinxi Chen, Masaaki Ohba, Susumu Kitagawa

Research output: Contribution to journalArticle

25 Citations (Scopus)

Abstract

Two new coordination polymers based on hexanuclear metal cluster cores, Zn6(HCOO)6(DBrTPA)3(DMF)6 (1) and Mn6(HCOO)6(BTC)2(DMF)6 (2) have been solvothermally synthesized. It is noteworthy that the formic ligands were in situ generated by the hydrolysis of DMF solvent under the solvothermal conditions and incorporated into these two compounds. The temperature-dependence of magnetic susceptibility for 2 shows antiferromagnetic interactions between metal centers.

Original languageEnglish
Pages (from-to)526-527
Number of pages2
JournalChemistry Letters
Volume35
Issue number5
DOIs
Publication statusPublished - May 5 2006
Externally publishedYes

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Polymers
Metals
Magnetic susceptibility
Hydrolysis
Ligands
Temperature
3'-dimethylaminoflavone

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

Cite this

Two new coordination polymers based on hexanuclear metal cluster cores. / Chen, Jinxi; Ohba, Masaaki; Kitagawa, Susumu.

In: Chemistry Letters, Vol. 35, No. 5, 05.05.2006, p. 526-527.

Research output: Contribution to journalArticle

Chen, Jinxi ; Ohba, Masaaki ; Kitagawa, Susumu. / Two new coordination polymers based on hexanuclear metal cluster cores. In: Chemistry Letters. 2006 ; Vol. 35, No. 5. pp. 526-527.
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