Ultraselective Gas Separation by Nanoporous Metal-Organic Frameworks Embedded in Gas-Barrier Nanocellulose Films

Makoto Matsumoto, Takuya Kitaoka

Research output: Contribution to journalArticle

41 Citations (Scopus)

Abstract

Metal-organic frameworks (MOFs) are synthesized at carboxy groups on crystalline TEMPO-oxidized cellulose nanofibers (TOCNs). MOF-TOCN films coated on a paper filter have a hierarchical structure from the nano-to macroscale, and demonstrate a high CO2/CH4 selectivity, over 120 for CO2 at a high gas flux, by the combination of the nanoporous MOFs and the gas-barrier TOCNs, which have strong affinity with each other.

Original languageEnglish
Pages (from-to)1765-1769
Number of pages5
JournalAdvanced Materials
Volume28
Issue number9
DOIs
Publication statusPublished - Mar 2 2016

Fingerprint

oxidized cellulose
Nanofibers
Cellulose
Gases
Metals
Fluxes
Crystalline materials
TEMPO

All Science Journal Classification (ASJC) codes

  • Materials Science(all)
  • Mechanics of Materials
  • Mechanical Engineering

Cite this

Ultraselective Gas Separation by Nanoporous Metal-Organic Frameworks Embedded in Gas-Barrier Nanocellulose Films. / Matsumoto, Makoto; Kitaoka, Takuya.

In: Advanced Materials, Vol. 28, No. 9, 02.03.2016, p. 1765-1769.

Research output: Contribution to journalArticle

@article{203c7086958d49a6abd63cedb5fba68c,
title = "Ultraselective Gas Separation by Nanoporous Metal-Organic Frameworks Embedded in Gas-Barrier Nanocellulose Films",
abstract = "Metal-organic frameworks (MOFs) are synthesized at carboxy groups on crystalline TEMPO-oxidized cellulose nanofibers (TOCNs). MOF-TOCN films coated on a paper filter have a hierarchical structure from the nano-to macroscale, and demonstrate a high CO2/CH4 selectivity, over 120 for CO2 at a high gas flux, by the combination of the nanoporous MOFs and the gas-barrier TOCNs, which have strong affinity with each other.",
author = "Makoto Matsumoto and Takuya Kitaoka",
year = "2016",
month = "3",
day = "2",
doi = "10.1002/adma.201504784",
language = "English",
volume = "28",
pages = "1765--1769",
journal = "Advanced Materials",
issn = "0935-9648",
publisher = "Wiley-VCH Verlag",
number = "9",

}

TY - JOUR

T1 - Ultraselective Gas Separation by Nanoporous Metal-Organic Frameworks Embedded in Gas-Barrier Nanocellulose Films

AU - Matsumoto, Makoto

AU - Kitaoka, Takuya

PY - 2016/3/2

Y1 - 2016/3/2

N2 - Metal-organic frameworks (MOFs) are synthesized at carboxy groups on crystalline TEMPO-oxidized cellulose nanofibers (TOCNs). MOF-TOCN films coated on a paper filter have a hierarchical structure from the nano-to macroscale, and demonstrate a high CO2/CH4 selectivity, over 120 for CO2 at a high gas flux, by the combination of the nanoporous MOFs and the gas-barrier TOCNs, which have strong affinity with each other.

AB - Metal-organic frameworks (MOFs) are synthesized at carboxy groups on crystalline TEMPO-oxidized cellulose nanofibers (TOCNs). MOF-TOCN films coated on a paper filter have a hierarchical structure from the nano-to macroscale, and demonstrate a high CO2/CH4 selectivity, over 120 for CO2 at a high gas flux, by the combination of the nanoporous MOFs and the gas-barrier TOCNs, which have strong affinity with each other.

UR - http://www.scopus.com/inward/record.url?scp=84959566413&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84959566413&partnerID=8YFLogxK

U2 - 10.1002/adma.201504784

DO - 10.1002/adma.201504784

M3 - Article

C2 - 26669724

AN - SCOPUS:84959566413

VL - 28

SP - 1765

EP - 1769

JO - Advanced Materials

JF - Advanced Materials

SN - 0935-9648

IS - 9

ER -