TY - JOUR
T1 - Ultrasonic study of gelation and vitrification in curing process of allyl-oligomer
AU - Okabe, Hirotaka
AU - Takashima, Wataru
AU - Taki, Seiji
AU - Matsushige, Kazumi
PY - 1991/1
Y1 - 1991/1
N2 - An automatic ultrasonic velocity measuring system was utilized to investigate an isothermal curing process of allyl-ester, a new thermosetting resin composed of an allyl-oligomer and a curing agent. The logarithmic curing time vs sound velocity curves showed apparent bends at curing temperatures below 140°C, while a monotonous relation above 150°C.The analysis based on a reaction rate equation suggested that such ultrasonic behavior resulted from the differentmechanism of gelation and/or vitrification, which became dominant depending on the curing temperature.
AB - An automatic ultrasonic velocity measuring system was utilized to investigate an isothermal curing process of allyl-ester, a new thermosetting resin composed of an allyl-oligomer and a curing agent. The logarithmic curing time vs sound velocity curves showed apparent bends at curing temperatures below 140°C, while a monotonous relation above 150°C.The analysis based on a reaction rate equation suggested that such ultrasonic behavior resulted from the differentmechanism of gelation and/or vitrification, which became dominant depending on the curing temperature.
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U2 - 10.7567/JJAPS.30S1.31
DO - 10.7567/JJAPS.30S1.31
M3 - Article
AN - SCOPUS:84956273835
VL - 30
SP - 31
EP - 33
JO - Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes
JF - Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes
SN - 0021-4922
ER -