Unique hydrogen bonding in the acetone-mediated helical structure of (R,R)-3,3′-bisBINOL

Toshio Kawanami, Kentaro Ishizuka, Hiroshi Furuno, Junji Inanaga

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

The asymmetric unit of the title compound, C40H 26C4·-2(CH3)2CO, consists of one molecule of (R,R)-3,3′-bisBINOL [(R,R)-1,1′:3′,3″: l″,1‴-quater-2-naphthol] and two acetone molecules. The central feature of the structure is the pair of unique sets of O-H⋯O⋯H-O hydrogen-bond arrangements between the two hydroxy groups of (R,R)-3,3′-bisBINOL and the O atom of acetone, which fixes the axial chirality of the 3,3′-bond as 5, thus maintaining the helical structure of the bisBINOL in the M form.

Original languageEnglish
Pages (from-to)o97-o98
JournalActa Crystallographica Section E: Structure Reports Online
Volume60
Issue number1
DOIs
Publication statusPublished - Jan 1 2004

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Hydrogen Bonding
Acetone
acetone
Hydrogen bonds
Naphthol
Molecules
Chirality
hydrogen
chirality
fixing
molecules
Hydrogen
hydrogen bonds
Atoms
atoms
2-naphthol

All Science Journal Classification (ASJC) codes

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

Unique hydrogen bonding in the acetone-mediated helical structure of (R,R)-3,3′-bisBINOL. / Kawanami, Toshio; Ishizuka, Kentaro; Furuno, Hiroshi; Inanaga, Junji.

In: Acta Crystallographica Section E: Structure Reports Online, Vol. 60, No. 1, 01.01.2004, p. o97-o98.

Research output: Contribution to journalArticle

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