Unique spin transition and wide thermal hysteresis loop for a cobalt(ii) compound with long alkyl chain

Shinya Hayami, Kazuya Kato, Yasuka Komatsu, Akira Fuyuhiro, Masaaki Ohba

Research output: Contribution to journalArticle

34 Citations (Scopus)

Abstract

The cobalt(ii) compounds with long alkyl chains, [Co(C12-terpy) 2](BF4)2·EtOH·0.5H 2O(1·EtOH·0.5H2O) and [Co(C12-terpy) 2](BF4)2 (1) was synthesized and characterized. The compound 1·EtOH·0.5H2O exhibits a "re-entrant spin crossover". The compound 1 exhibits the reentrant spin crossover and multi phase transitions with a wide thermal hysteresis loop.

Original languageEnglish
Pages (from-to)2167-2169
Number of pages3
JournalDalton Transactions
Volume40
Issue number10
DOIs
Publication statusPublished - Mar 14 2011

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Cobalt compounds
Hysteresis loops
Phase transitions
Hot Temperature

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

Unique spin transition and wide thermal hysteresis loop for a cobalt(ii) compound with long alkyl chain. / Hayami, Shinya; Kato, Kazuya; Komatsu, Yasuka; Fuyuhiro, Akira; Ohba, Masaaki.

In: Dalton Transactions, Vol. 40, No. 10, 14.03.2011, p. 2167-2169.

Research output: Contribution to journalArticle

Hayami, Shinya ; Kato, Kazuya ; Komatsu, Yasuka ; Fuyuhiro, Akira ; Ohba, Masaaki. / Unique spin transition and wide thermal hysteresis loop for a cobalt(ii) compound with long alkyl chain. In: Dalton Transactions. 2011 ; Vol. 40, No. 10. pp. 2167-2169.
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