Unique spin transition and wide thermal hysteresis loop for a cobalt(ii) compound with long alkyl chain

Shinya Hayami, Kazuya Kato, Yasuka Komatsu, Akira Fuyuhiro, Masaaki Ohba

Research output: Contribution to journalArticle

36 Citations (Scopus)

Abstract

The cobalt(ii) compounds with long alkyl chains, [Co(C12-terpy) 2](BF4)2·EtOH·0.5H 2O(1·EtOH·0.5H2O) and [Co(C12-terpy) 2](BF4)2 (1) was synthesized and characterized. The compound 1·EtOH·0.5H2O exhibits a "re-entrant spin crossover". The compound 1 exhibits the reentrant spin crossover and multi phase transitions with a wide thermal hysteresis loop.

Original languageEnglish
Pages (from-to)2167-2169
Number of pages3
JournalDalton Transactions
Volume40
Issue number10
DOIs
Publication statusPublished - Mar 14 2011

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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