The cobalt(ii) compounds with long alkyl chains, [Co(C12-terpy) 2](BF4)2·EtOH·0.5H 2O(1·EtOH·0.5H2O) and [Co(C12-terpy) 2](BF4)2 (1) was synthesized and characterized. The compound 1·EtOH·0.5H2O exhibits a "re-entrant spin crossover". The compound 1 exhibits the reentrant spin crossover and multi phase transitions with a wide thermal hysteresis loop.
All Science Journal Classification (ASJC) codes
- Inorganic Chemistry