Unprecedented 1,4-methyl group migration in a rhodium-catalysed hydrosilylation of ketones by 1,2-bis(dimethylsilyl)benzene

Hideo Nagashima, Kazuo Tatebe, Kenji Itoh

Research output: Contribution to journalArticle

15 Citations (Scopus)

Abstract

A rhodium-catalyzed hydrosilylation of ketones afforded a mixture of alkoxysilanes, 1-(ROSiMe2)-2-(HMe2Si)C6H 4 and 1-(ROSiHMe)-2-(Me3Si)C6H4; the latter resulted by 1,4-methyl group migration during the hydrosilylation.

Original languageEnglish
Pages (from-to)1707-1708
Number of pages2
JournalJournal of the Chemical Society, Perkin Transactions 1
Issue number9
Publication statusPublished - Dec 1 1989
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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