Unprecedented formation of a rhodium cluster triggered by rhodium-fastened N-confused gable porphyrin

Motoki Toganoh, Teppei Niino, Hiromitsu Maeda, Bruno Andrioletti, Hiroyuki Furuta

Research output: Contribution to journalArticle

19 Citations (Scopus)

Abstract

Thermal reaction of N-confused porphyrin (NCP) with [RhCl(CO) 2]2 caused unprecedented formation of tetranuclear rhodium complex Rh4(NCP)2(CO)4 having a gable-porphyrin-type structure, where two porphyrin π systems were electronically connected by the rhodium cluster.

Original languageEnglish
Pages (from-to)10428-10430
Number of pages3
JournalInorganic chemistry
Volume45
Issue number26
DOIs
Publication statusPublished - Dec 25 2006

    Fingerprint

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

Cite this