Unprecedented formation of a rhodium cluster triggered by rhodium-fastened N-confused gable porphyrin

Motoki Toganoh, Teppei Niino, Hiromitsu Maeda, Bruno Andrioletti, Hiroyuki Furuta

    Research output: Contribution to journalArticlepeer-review

    21 Citations (Scopus)

    Abstract

    Thermal reaction of N-confused porphyrin (NCP) with [RhCl(CO) 2]2 caused unprecedented formation of tetranuclear rhodium complex Rh4(NCP)2(CO)4 having a gable-porphyrin-type structure, where two porphyrin π systems were electronically connected by the rhodium cluster.

    Original languageEnglish
    Pages (from-to)10428-10430
    Number of pages3
    JournalInorganic chemistry
    Volume45
    Issue number26
    DOIs
    Publication statusPublished - Dec 25 2006

    All Science Journal Classification (ASJC) codes

    • Physical and Theoretical Chemistry
    • Inorganic Chemistry

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