Unstable and Stable Thermal Hysteresis Under Thermal Triangle Waves

Mieko Arisawa, Rina Iwamoto, Masahiko Yamaguchi

Research output: Contribution to journalArticlepeer-review

1 Citation (Scopus)

Abstract

A 1 : 1 mixture of aminomethylenehelicene (P)-tetramer with C16 alkyl groups (P)-1-C16 and (M)-pentamer (M)-2 in fluorobenzene forms hetero-double-helices, and the processes of formation and dissociation exhibit thermal hysteresis on cooling and heating. When thermal triangle waves with repeated cooling and heating cycles are applied, unstable thermal hysteresis appears, which becomes a stable thermal hysteresis after sufficient numbers of cycles. The phenomenon of middle-range stable thermal hysteresis is observed in this case. Properties of unstable and stable thermal hysteresis are examined under various thermal triangle waves.

Original languageEnglish
Pages (from-to)4461-4465
Number of pages5
JournalChemistrySelect
Volume6
Issue number18
DOIs
Publication statusPublished - May 14 2021

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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