Unusual motion of then-methoxypropyl moiety observed in the photochromic crystals of an organorhodium dithionite complex withn-methoxypropyltetramethylcyclopentadienyl ligands

Yuu Kajiwara; Seiya Miyata; Hidetaka Nakai

doi:10.1039/d1dt03347f

Unusual motion of then-methoxypropyl moiety observed in the photochromic crystals of an organorhodium dithionite complex withn-methoxypropyltetramethylcyclopentadienyl ligands

Yuu Kajiwara, Seiya Miyata, Hidetaka Nakai

Research output: Contribution to journal › Article › peer-review

1 Citation (Scopus)

Abstract

The crystalline-state photochromism of a new organorhodium dinuclear complex havingn-methoxypropyltetramethylcyclopentadienyl (η⁵-C₅Me₄n-C₃H₆OCH₃) and photoresponsive dithionite (μ-O₂SSO₂) ligands was investigated directly by performing single-crystal X-ray diffraction experiments; a reversible conformational change of then-methoxypropyl moiety was intriguingly observed during the course of a thermal back-reaction.

Original language	English
Pages (from-to)	48-52
Number of pages	5
Journal	Dalton Transactions
Volume	51
Issue number	1
DOIs	https://doi.org/10.1039/d1dt03347f
Publication status	Published - Jan 7 2022
Externally published	Yes

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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abstract = "The crystalline-state photochromism of a new organorhodium dinuclear complex havingn-methoxypropyltetramethylcyclopentadienyl (η5-C5Me4n-C3H6OCH3) and photoresponsive dithionite (μ-O2SSO2) ligands was investigated directly by performing single-crystal X-ray diffraction experiments; a reversible conformational change of then-methoxypropyl moiety was intriguingly observed during the course of a thermal back-reaction.",

author = "Yuu Kajiwara and Seiya Miyata and Hidetaka Nakai",

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AU - Kajiwara, Yuu

AU - Miyata, Seiya

AU - Nakai, Hidetaka

N1 - Funding Information: This work was supported by the JSPS KAKENHI Grant Number JP21K05103. We would like to thank Mr Takuya Kishimoto (Kindai Univ.) for his help in the synthesis of the compounds. Publisher Copyright: © The Royal Society of Chemistry 2021.

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AB - The crystalline-state photochromism of a new organorhodium dinuclear complex havingn-methoxypropyltetramethylcyclopentadienyl (η5-C5Me4n-C3H6OCH3) and photoresponsive dithionite (μ-O2SSO2) ligands was investigated directly by performing single-crystal X-ray diffraction experiments; a reversible conformational change of then-methoxypropyl moiety was intriguingly observed during the course of a thermal back-reaction.

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Unusual motion of then-methoxypropyl moiety observed in the photochromic crystals of an organorhodium dithionite complex withn-methoxypropyltetramethylcyclopentadienyl ligands

Abstract

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