Utilization of industrially available 2,3-dichloro-1,3-butadiene for direct synthesis of 2,3-diaryl-1,3-butadienes

Takakazu Yamamoto, Takuma Yasuda, Kazuaki Kobayashi, Isao Yamaguchi, Take Aki Koizumi, Daisuke Ishii, Masaru Nakagawa, Yoshihiro Mashiko, Norihiro Shimizu

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Abstract

It is shown that industrially available 2,3-dichloro-1,3-butadiene is a useful starting material for the synthesis of 2,3-diaryl-1,3-butadienes. Ni(II)-catalyzed cross-coupling reaction of 2,3-dichloro-1,3-butadiene with ArMgBr (Ar = 2-thienyl, phenyl, 4-dodecyloxyphenyl, and 4-fluorophenyl) gives the corresponding 2,3-diaryl-1,3-butadienes in good yields.

Original languageEnglish
Pages (from-to)498-500
Number of pages3
JournalBulletin of the Chemical Society of Japan
Volume79
Issue number3
DOIs
Publication statusPublished - Nov 7 2006

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1,3-butadiene
2,3-dichloro-1,3-butadiene

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

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Utilization of industrially available 2,3-dichloro-1,3-butadiene for direct synthesis of 2,3-diaryl-1,3-butadienes. / Yamamoto, Takakazu; Yasuda, Takuma; Kobayashi, Kazuaki; Yamaguchi, Isao; Koizumi, Take Aki; Ishii, Daisuke; Nakagawa, Masaru; Mashiko, Yoshihiro; Shimizu, Norihiro.

In: Bulletin of the Chemical Society of Japan, Vol. 79, No. 3, 07.11.2006, p. 498-500.

Research output: Contribution to journalArticle

Yamamoto, T, Yasuda, T, Kobayashi, K, Yamaguchi, I, Koizumi, TA, Ishii, D, Nakagawa, M, Mashiko, Y & Shimizu, N 2006, 'Utilization of industrially available 2,3-dichloro-1,3-butadiene for direct synthesis of 2,3-diaryl-1,3-butadienes', Bulletin of the Chemical Society of Japan, vol. 79, no. 3, pp. 498-500. https://doi.org/10.1246/bcsj.79.498
Yamamoto, Takakazu ; Yasuda, Takuma ; Kobayashi, Kazuaki ; Yamaguchi, Isao ; Koizumi, Take Aki ; Ishii, Daisuke ; Nakagawa, Masaru ; Mashiko, Yoshihiro ; Shimizu, Norihiro. / Utilization of industrially available 2,3-dichloro-1,3-butadiene for direct synthesis of 2,3-diaryl-1,3-butadienes. In: Bulletin of the Chemical Society of Japan. 2006 ; Vol. 79, No. 3. pp. 498-500.
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AU - Kobayashi, Kazuaki

AU - Yamaguchi, Isao

AU - Koizumi, Take Aki

AU - Ishii, Daisuke

AU - Nakagawa, Masaru

AU - Mashiko, Yoshihiro

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