Valence tautomeric transitions with thermal hysteresis around room temperature and photoinduced effects observed in a cobalt-tetraoxolene complex

Jun Tao, Hiroyuki Maruyama, Osamu Sato

Research output: Contribution to journalArticle

153 Citations (Scopus)

Abstract

A dinuclear complex, [(CoTPA)2(DHBQ)](PF6)3, has been successfully synthesized that exhibits a valence tautomeric transition with a distinct hysteresis effect (13 K) around room temperature and photoinduced valence tautomerism under low temperature.

Original languageEnglish
Pages (from-to)1790-1791
Number of pages2
JournalJournal of the American Chemical Society
Volume128
Issue number6
DOIs
Publication statusPublished - Feb 15 2006

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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