Vibrational spectrum ofsin the p-tert-butylcalix[8]arene(1:1scomplex

B. Paci, G. Amoretti, G. Arduini, G. Ruani, S. Shinkai, T. Suzuki, F. Ugozzoli, R. Caciuffo

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Abstract

We report the results of Raman, infrared, and inelastic neutron scattering investigations of the vibrational spectrum of the complex p-tert-butylcalix[8]arene(1:1)fullerene, a system with almost isolated (Formula presented) molecules confined inside neutral cages. All the internal optical-active modes of the (Formula presented) guest have been identified, and further modes which can be attributed to (Formula presented) intramolecular vibrations appear in the neutron scattering function. A comparison with the vibrational spectrum of empty p-tert-butylcalix[8]arene indicates that the host-guest interaction is very weak. As solid-state effects are also practically suppressed, the investigated complex gives the unique opportunity to study almost free fullerene balls confined in the solid state.

Original languageEnglish
Pages (from-to)5566-5569
Number of pages4
JournalPhysical Review B - Condensed Matter and Materials Physics
Volume55
Issue number9
DOIs
Publication statusPublished - 1997

All Science Journal Classification (ASJC) codes

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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    Paci, B., Amoretti, G., Arduini, G., Ruani, G., Shinkai, S., Suzuki, T., Ugozzoli, F., & Caciuffo, R. (1997). Vibrational spectrum ofsin the p-tert-butylcalix[8]arene(1:1scomplex. Physical Review B - Condensed Matter and Materials Physics, 55(9), 5566-5569. https://doi.org/10.1103/PhysRevB.55.5566