Water-dependent charge-transfer-induced spin transition of Prussian blue analogues

Hitomi Ohmagari, Ryo Ohtani, Manabu Nakaya, Masaaki Ohba, Masaaki Nakamura, Leonard F. Lindoy, Osamu Sato, Shinya Hayami

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

Cobalt-iron Prussian blue analogues are magnetic functional compounds that exhibit charge-transfer-induced spin transition (CTIST), however, the role of guest species such as water in influencing the magnetic behaviour has remained unclear. Here, we report the water-dependent CTIST behaviour of Na0.46Co[Fe(CN)6]0.78(H2O)1.31 together with its single crystal X-ray structural analysis, for the first time.

Original languageEnglish
Pages (from-to)16784-16788
Number of pages5
JournalDalton Transactions
Volume45
Issue number42
DOIs
Publication statusPublished - Jan 1 2016

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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