Wheel-type heterometallic ferromagnetic clusters: [Ni7−xMx(HL)63-OMe)43-OH)2]Cl2 (M = Zn, Co, Mn; x = 1, 3)

Fumiya Kobayashi, Ryo Ohtani, Sotaro Kusumoto, Leonard F. Lindoy, Shinya Hayami, Masaaki Nakamura

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

Wheel-type heptanuclear heterometallic clusters of stoichiometry [Ni7−xMx(HL)63-OMe)43-OH)2]Cl2 (L = 1-(2-hydroxy-3-methoxybenzamido)-2-(benzylideneamino)ethane; M = Zn2+, Co2+, Mn2+; x = 1, 3) were synthesized, and their metal ion dependent ferromagnetic properties were investigated. It was demonstrated that the central position of each cluster was occupied by a Ni2+ ion while other metal ions (Zn2+, Co2+ or Mn2+) were accommodated in peripheral positions. The magnetic interactions, anisotropy and magnetization of the resultant clusters were all influenced by the combinations of metal ions present.

Original languageEnglish
Pages (from-to)16422-16428
Number of pages7
JournalDalton Transactions
Volume47
Issue number46
DOIs
Publication statusPublished - 2018
Externally publishedYes

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

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