Wheel-type heterometallic ferromagnetic clusters

[Ni7−xMx(HL)63-OMe)43-OH)2]Cl2 (M = Zn, Co, Mn; x = 1, 3)

Fumiya Kobayashi, Ryo Otani, Sotaro Kusumoto, Leonard F. Lindoy, Shinya Hayami, Masaaki Nakamura

Research output: Contribution to journalArticle

Abstract

Wheel-type heptanuclear heterometallic clusters of stoichiometry [Ni7−xMx(HL)63-OMe)43-OH)2]Cl2 (L = 1-(2-hydroxy-3-methoxybenzamido)-2-(benzylideneamino)ethane; M = Zn2+, Co2+, Mn2+; x = 1, 3) were synthesized, and their metal ion dependent ferromagnetic properties were investigated. It was demonstrated that the central position of each cluster was occupied by a Ni2+ ion while other metal ions (Zn2+, Co2+ or Mn2+) were accommodated in peripheral positions. The magnetic interactions, anisotropy and magnetization of the resultant clusters were all influenced by the combinations of metal ions present.

Original languageEnglish
Pages (from-to)16422-16428
Number of pages7
JournalDalton Transactions
Volume47
Issue number46
DOIs
Publication statusPublished - Jan 1 2018
Externally publishedYes

Fingerprint

Metal ions
Wheels
Ethane
Stoichiometry
Magnetization
Anisotropy
Ions

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Cite this

Wheel-type heterometallic ferromagnetic clusters : [Ni7−xMx(HL)63-OMe)43-OH)2]Cl2 (M = Zn, Co, Mn; x = 1, 3). / Kobayashi, Fumiya; Otani, Ryo; Kusumoto, Sotaro; Lindoy, Leonard F.; Hayami, Shinya; Nakamura, Masaaki.

In: Dalton Transactions, Vol. 47, No. 46, 01.01.2018, p. 16422-16428.

Research output: Contribution to journalArticle

Kobayashi, Fumiya ; Otani, Ryo ; Kusumoto, Sotaro ; Lindoy, Leonard F. ; Hayami, Shinya ; Nakamura, Masaaki. / Wheel-type heterometallic ferromagnetic clusters : [Ni7−xMx(HL)63-OMe)43-OH)2]Cl2 (M = Zn, Co, Mn; x = 1, 3). In: Dalton Transactions. 2018 ; Vol. 47, No. 46. pp. 16422-16428.
@article{d4b284cf40b549b38a77dc8c140dedde,
title = "Wheel-type heterometallic ferromagnetic clusters: [Ni7−xMx(HL)6(μ3-OMe)4(μ3-OH)2]Cl2 (M = Zn, Co, Mn; x = 1, 3)",
abstract = "Wheel-type heptanuclear heterometallic clusters of stoichiometry [Ni7−xMx(HL)6(μ3-OMe)4(μ3-OH)2]Cl2 (L = 1-(2-hydroxy-3-methoxybenzamido)-2-(benzylideneamino)ethane; M = Zn2+, Co2+, Mn2+; x = 1, 3) were synthesized, and their metal ion dependent ferromagnetic properties were investigated. It was demonstrated that the central position of each cluster was occupied by a Ni2+ ion while other metal ions (Zn2+, Co2+ or Mn2+) were accommodated in peripheral positions. The magnetic interactions, anisotropy and magnetization of the resultant clusters were all influenced by the combinations of metal ions present.",
author = "Fumiya Kobayashi and Ryo Otani and Sotaro Kusumoto and Lindoy, {Leonard F.} and Shinya Hayami and Masaaki Nakamura",
year = "2018",
month = "1",
day = "1",
doi = "10.1039/c8dt03275k",
language = "English",
volume = "47",
pages = "16422--16428",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "46",

}

TY - JOUR

T1 - Wheel-type heterometallic ferromagnetic clusters

T2 - [Ni7−xMx(HL)6(μ3-OMe)4(μ3-OH)2]Cl2 (M = Zn, Co, Mn; x = 1, 3)

AU - Kobayashi, Fumiya

AU - Otani, Ryo

AU - Kusumoto, Sotaro

AU - Lindoy, Leonard F.

AU - Hayami, Shinya

AU - Nakamura, Masaaki

PY - 2018/1/1

Y1 - 2018/1/1

N2 - Wheel-type heptanuclear heterometallic clusters of stoichiometry [Ni7−xMx(HL)6(μ3-OMe)4(μ3-OH)2]Cl2 (L = 1-(2-hydroxy-3-methoxybenzamido)-2-(benzylideneamino)ethane; M = Zn2+, Co2+, Mn2+; x = 1, 3) were synthesized, and their metal ion dependent ferromagnetic properties were investigated. It was demonstrated that the central position of each cluster was occupied by a Ni2+ ion while other metal ions (Zn2+, Co2+ or Mn2+) were accommodated in peripheral positions. The magnetic interactions, anisotropy and magnetization of the resultant clusters were all influenced by the combinations of metal ions present.

AB - Wheel-type heptanuclear heterometallic clusters of stoichiometry [Ni7−xMx(HL)6(μ3-OMe)4(μ3-OH)2]Cl2 (L = 1-(2-hydroxy-3-methoxybenzamido)-2-(benzylideneamino)ethane; M = Zn2+, Co2+, Mn2+; x = 1, 3) were synthesized, and their metal ion dependent ferromagnetic properties were investigated. It was demonstrated that the central position of each cluster was occupied by a Ni2+ ion while other metal ions (Zn2+, Co2+ or Mn2+) were accommodated in peripheral positions. The magnetic interactions, anisotropy and magnetization of the resultant clusters were all influenced by the combinations of metal ions present.

UR - http://www.scopus.com/inward/record.url?scp=85057208328&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=85057208328&partnerID=8YFLogxK

U2 - 10.1039/c8dt03275k

DO - 10.1039/c8dt03275k

M3 - Article

VL - 47

SP - 16422

EP - 16428

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 46

ER -