Wide polarized potential windows at the interface between water and an ionic liquid, tetraheptylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Ryoichi Ishimatsu; Naoya Nishi; Takashi Kakiuchi

doi:10.1246/cl.2007.1166

Wide polarized potential windows at the interface between water and an ionic liquid, tetraheptylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Ryoichi Ishimatsu, Naoya Nishi, Takashi Kakiuchi

Research output: Contribution to journal › Article › peer-review

16 Citations (Scopus)

Abstract

Wide polarized potential windows against interfacial ion transfer are available at the interface between a hydrophobic ionic liquid (IL), tetraheptylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate ([THpA ⁺][TFPB^-]) and an aqueous electrolyte solution (W) of MgSO₄. The width of the potential window, 1.1V at 60°C, enables electrochemical studies of charge transfer at the IL/W interface for a variety of ions and redox couples.

Original language	English
Pages (from-to)	1166-1167
Number of pages	2
Journal	Chemistry Letters
Volume	36
Issue number	9
DOIs	https://doi.org/10.1246/cl.2007.1166
Publication status	Published - Sept 5 2007
Externally published	Yes

All Science Journal Classification (ASJC) codes

Chemistry(all)

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10.1246/cl.2007.1166

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abstract = "Wide polarized potential windows against interfacial ion transfer are available at the interface between a hydrophobic ionic liquid (IL), tetraheptylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate ([THpA +][TFPB-]) and an aqueous electrolyte solution (W) of MgSO4. The width of the potential window, 1.1V at 60°C, enables electrochemical studies of charge transfer at the IL/W interface for a variety of ions and redox couples.",

author = "Ryoichi Ishimatsu and Naoya Nishi and Takashi Kakiuchi",

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T1 - Wide polarized potential windows at the interface between water and an ionic liquid, tetraheptylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

AU - Ishimatsu, Ryoichi

AU - Nishi, Naoya

AU - Kakiuchi, Takashi

PY - 2007/9/5

Y1 - 2007/9/5

N2 - Wide polarized potential windows against interfacial ion transfer are available at the interface between a hydrophobic ionic liquid (IL), tetraheptylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate ([THpA +][TFPB-]) and an aqueous electrolyte solution (W) of MgSO4. The width of the potential window, 1.1V at 60°C, enables electrochemical studies of charge transfer at the IL/W interface for a variety of ions and redox couples.

AB - Wide polarized potential windows against interfacial ion transfer are available at the interface between a hydrophobic ionic liquid (IL), tetraheptylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate ([THpA +][TFPB-]) and an aqueous electrolyte solution (W) of MgSO4. The width of the potential window, 1.1V at 60°C, enables electrochemical studies of charge transfer at the IL/W interface for a variety of ions and redox couples.

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Wide polarized potential windows at the interface between water and an ionic liquid, tetraheptylammonium tetrakis[3,5-bis(trifluoromethyl)phenyl]borate

Abstract

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