X-ray photoemission spectroscopy and Fourier transform infrared studies of electrochemical doping of copper phthalocyanine molecule in conducting polymer

H. Kato, S. Takemura, Y. Watanabe, A. Ishii, I. Tsuchida, Y. Akai, Takeharu Sugiyama, T. Hiramatsu, N. Nanba, O. Nishikawa, M. Taniguchi

Research output: Contribution to journalArticle

11 Citations (Scopus)

Abstract

A conducting polymer polythiophene (PT) film incorporated with copper phthalocyanine (CuPc), which was a highly functional molecule, was synthesized and characterized by Fourier transform infrared (FTIR) spectroscopy and x-ray photoemission spectroscopy (XPS). Electrochemical and casting processes were developed as a doping method of CuPc molecules in a PT film. In the XPS measurements of the CuPc doped PT, CuPc-origin peaks on the higher energy side appeared in the C 1s spectrum. The C 1s spectral profiles between electrochemically doped and cast samples were different in the higher binding energy region. S 2p and N 1s core-level spectra of CuPc doped compounds also showed the difference of the spectral profile between electrochemically doped and cast samples, which suggested the dopant-polymer interaction. A split of Cu 2p spectra indicates the charge transfer between CuPc and the polymer chains. In the FTIR measurements, characteristic vibrational modes to CuPc, in-plane, out-of-plane, and ring stretching modes were observed. A central metal-origin peak was also observed. New peaks at 1545 and 1680 cm-1 suggest the polymer-PcCu linkage.

Original languageEnglish
Pages (from-to)1147-1151
Number of pages5
JournalJournal of Vacuum Science and Technology A: Vacuum, Surfaces and Films
Volume25
Issue number4
DOIs
Publication statusPublished - Aug 2 2007

Fingerprint

Conducting polymers
conducting polymers
Photoelectron spectroscopy
X ray spectroscopy
Fourier transforms
Polymers
photoelectric emission
Doping (additives)
Infrared radiation
Copper
copper
Molecules
casts
polymers
spectroscopy
molecules
X rays
x rays
Core levels
profiles

All Science Journal Classification (ASJC) codes

  • Condensed Matter Physics
  • Surfaces and Interfaces
  • Surfaces, Coatings and Films

Cite this

X-ray photoemission spectroscopy and Fourier transform infrared studies of electrochemical doping of copper phthalocyanine molecule in conducting polymer. / Kato, H.; Takemura, S.; Watanabe, Y.; Ishii, A.; Tsuchida, I.; Akai, Y.; Sugiyama, Takeharu; Hiramatsu, T.; Nanba, N.; Nishikawa, O.; Taniguchi, M.

In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films, Vol. 25, No. 4, 02.08.2007, p. 1147-1151.

Research output: Contribution to journalArticle

Kato, H. ; Takemura, S. ; Watanabe, Y. ; Ishii, A. ; Tsuchida, I. ; Akai, Y. ; Sugiyama, Takeharu ; Hiramatsu, T. ; Nanba, N. ; Nishikawa, O. ; Taniguchi, M. / X-ray photoemission spectroscopy and Fourier transform infrared studies of electrochemical doping of copper phthalocyanine molecule in conducting polymer. In: Journal of Vacuum Science and Technology A: Vacuum, Surfaces and Films. 2007 ; Vol. 25, No. 4. pp. 1147-1151.
@article{739792ae62bc43aeb0b514ea6bd63a44,
title = "X-ray photoemission spectroscopy and Fourier transform infrared studies of electrochemical doping of copper phthalocyanine molecule in conducting polymer",
abstract = "A conducting polymer polythiophene (PT) film incorporated with copper phthalocyanine (CuPc), which was a highly functional molecule, was synthesized and characterized by Fourier transform infrared (FTIR) spectroscopy and x-ray photoemission spectroscopy (XPS). Electrochemical and casting processes were developed as a doping method of CuPc molecules in a PT film. In the XPS measurements of the CuPc doped PT, CuPc-origin peaks on the higher energy side appeared in the C 1s spectrum. The C 1s spectral profiles between electrochemically doped and cast samples were different in the higher binding energy region. S 2p and N 1s core-level spectra of CuPc doped compounds also showed the difference of the spectral profile between electrochemically doped and cast samples, which suggested the dopant-polymer interaction. A split of Cu 2p spectra indicates the charge transfer between CuPc and the polymer chains. In the FTIR measurements, characteristic vibrational modes to CuPc, in-plane, out-of-plane, and ring stretching modes were observed. A central metal-origin peak was also observed. New peaks at 1545 and 1680 cm-1 suggest the polymer-PcCu linkage.",
author = "H. Kato and S. Takemura and Y. Watanabe and A. Ishii and I. Tsuchida and Y. Akai and Takeharu Sugiyama and T. Hiramatsu and N. Nanba and O. Nishikawa and M. Taniguchi",
year = "2007",
month = "8",
day = "2",
doi = "10.1116/1.2731347",
language = "English",
volume = "25",
pages = "1147--1151",
journal = "Journal of Vacuum Science and Technology A",
issn = "0734-2101",
publisher = "AVS Science and Technology Society",
number = "4",

}

TY - JOUR

T1 - X-ray photoemission spectroscopy and Fourier transform infrared studies of electrochemical doping of copper phthalocyanine molecule in conducting polymer

AU - Kato, H.

AU - Takemura, S.

AU - Watanabe, Y.

AU - Ishii, A.

AU - Tsuchida, I.

AU - Akai, Y.

AU - Sugiyama, Takeharu

AU - Hiramatsu, T.

AU - Nanba, N.

AU - Nishikawa, O.

AU - Taniguchi, M.

PY - 2007/8/2

Y1 - 2007/8/2

N2 - A conducting polymer polythiophene (PT) film incorporated with copper phthalocyanine (CuPc), which was a highly functional molecule, was synthesized and characterized by Fourier transform infrared (FTIR) spectroscopy and x-ray photoemission spectroscopy (XPS). Electrochemical and casting processes were developed as a doping method of CuPc molecules in a PT film. In the XPS measurements of the CuPc doped PT, CuPc-origin peaks on the higher energy side appeared in the C 1s spectrum. The C 1s spectral profiles between electrochemically doped and cast samples were different in the higher binding energy region. S 2p and N 1s core-level spectra of CuPc doped compounds also showed the difference of the spectral profile between electrochemically doped and cast samples, which suggested the dopant-polymer interaction. A split of Cu 2p spectra indicates the charge transfer between CuPc and the polymer chains. In the FTIR measurements, characteristic vibrational modes to CuPc, in-plane, out-of-plane, and ring stretching modes were observed. A central metal-origin peak was also observed. New peaks at 1545 and 1680 cm-1 suggest the polymer-PcCu linkage.

AB - A conducting polymer polythiophene (PT) film incorporated with copper phthalocyanine (CuPc), which was a highly functional molecule, was synthesized and characterized by Fourier transform infrared (FTIR) spectroscopy and x-ray photoemission spectroscopy (XPS). Electrochemical and casting processes were developed as a doping method of CuPc molecules in a PT film. In the XPS measurements of the CuPc doped PT, CuPc-origin peaks on the higher energy side appeared in the C 1s spectrum. The C 1s spectral profiles between electrochemically doped and cast samples were different in the higher binding energy region. S 2p and N 1s core-level spectra of CuPc doped compounds also showed the difference of the spectral profile between electrochemically doped and cast samples, which suggested the dopant-polymer interaction. A split of Cu 2p spectra indicates the charge transfer between CuPc and the polymer chains. In the FTIR measurements, characteristic vibrational modes to CuPc, in-plane, out-of-plane, and ring stretching modes were observed. A central metal-origin peak was also observed. New peaks at 1545 and 1680 cm-1 suggest the polymer-PcCu linkage.

UR - http://www.scopus.com/inward/record.url?scp=34547244637&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=34547244637&partnerID=8YFLogxK

U2 - 10.1116/1.2731347

DO - 10.1116/1.2731347

M3 - Article

VL - 25

SP - 1147

EP - 1151

JO - Journal of Vacuum Science and Technology A

JF - Journal of Vacuum Science and Technology A

SN - 0734-2101

IS - 4

ER -