Zinc complex of N-confused calix[4]phyrin

Hiroyuki Furuta, Tomoya Ishizuka, Atsuhiro Osuka

Research output: Contribution to journalArticle

26 Citations (Scopus)

Abstract

A zinc(II) complex of N-confused calix[4]phyrin (isoporphyrin) (2-Zn) has been synthesized and the structure was revealed by 1H NMR and X-ray analyses. The atomic distance between zinc metal and the inner-core carbon was about 0.2 Å longer compared with that of zinc(II) N-confused porphyrin complexes, suggesting the weaker side-on η1-coordination with the inner-core-carbon in 2-Zn.

Original languageEnglish
Pages (from-to)398-401
Number of pages4
JournalInorganic Chemistry Communications
Volume6
Issue number4
DOIs
Publication statusPublished - Apr 1 2003

Fingerprint

Zinc
zinc
Carbon
carbon
Porphyrins
porphyrins
Metals
Nuclear magnetic resonance
X rays
nuclear magnetic resonance
metals
x rays

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

Zinc complex of N-confused calix[4]phyrin. / Furuta, Hiroyuki; Ishizuka, Tomoya; Osuka, Atsuhiro.

In: Inorganic Chemistry Communications, Vol. 6, No. 4, 01.04.2003, p. 398-401.

Research output: Contribution to journalArticle

Furuta, Hiroyuki ; Ishizuka, Tomoya ; Osuka, Atsuhiro. / Zinc complex of N-confused calix[4]phyrin. In: Inorganic Chemistry Communications. 2003 ; Vol. 6, No. 4. pp. 398-401.
@article{a5401071612c493699665a3cc98cbcca,
title = "Zinc complex of N-confused calix[4]phyrin",
abstract = "A zinc(II) complex of N-confused calix[4]phyrin (isoporphyrin) (2-Zn) has been synthesized and the structure was revealed by 1H NMR and X-ray analyses. The atomic distance between zinc metal and the inner-core carbon was about 0.2 {\AA} longer compared with that of zinc(II) N-confused porphyrin complexes, suggesting the weaker side-on η1-coordination with the inner-core-carbon in 2-Zn.",
author = "Hiroyuki Furuta and Tomoya Ishizuka and Atsuhiro Osuka",
year = "2003",
month = "4",
day = "1",
doi = "10.1016/S1387-7003(02)00797-9",
language = "English",
volume = "6",
pages = "398--401",
journal = "Inorganic Chemistry Communication",
issn = "1387-7003",
publisher = "Elsevier BV",
number = "4",

}

TY - JOUR

T1 - Zinc complex of N-confused calix[4]phyrin

AU - Furuta, Hiroyuki

AU - Ishizuka, Tomoya

AU - Osuka, Atsuhiro

PY - 2003/4/1

Y1 - 2003/4/1

N2 - A zinc(II) complex of N-confused calix[4]phyrin (isoporphyrin) (2-Zn) has been synthesized and the structure was revealed by 1H NMR and X-ray analyses. The atomic distance between zinc metal and the inner-core carbon was about 0.2 Å longer compared with that of zinc(II) N-confused porphyrin complexes, suggesting the weaker side-on η1-coordination with the inner-core-carbon in 2-Zn.

AB - A zinc(II) complex of N-confused calix[4]phyrin (isoporphyrin) (2-Zn) has been synthesized and the structure was revealed by 1H NMR and X-ray analyses. The atomic distance between zinc metal and the inner-core carbon was about 0.2 Å longer compared with that of zinc(II) N-confused porphyrin complexes, suggesting the weaker side-on η1-coordination with the inner-core-carbon in 2-Zn.

UR - http://www.scopus.com/inward/record.url?scp=0037395779&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0037395779&partnerID=8YFLogxK

U2 - 10.1016/S1387-7003(02)00797-9

DO - 10.1016/S1387-7003(02)00797-9

M3 - Article

VL - 6

SP - 398

EP - 401

JO - Inorganic Chemistry Communication

JF - Inorganic Chemistry Communication

SN - 1387-7003

IS - 4

ER -