Zinc complex of N-confused calix[4]phyrin

Hiroyuki Furuta, Tomoya Ishizuka, Atsuhiro Osuka

    Research output: Contribution to journalArticlepeer-review

    31 Citations (Scopus)

    Abstract

    A zinc(II) complex of N-confused calix[4]phyrin (isoporphyrin) (2-Zn) has been synthesized and the structure was revealed by 1H NMR and X-ray analyses. The atomic distance between zinc metal and the inner-core carbon was about 0.2 Å longer compared with that of zinc(II) N-confused porphyrin complexes, suggesting the weaker side-on η1-coordination with the inner-core-carbon in 2-Zn.

    Original languageEnglish
    Pages (from-to)398-401
    Number of pages4
    JournalInorganic Chemistry Communications
    Volume6
    Issue number4
    DOIs
    Publication statusPublished - Apr 1 2003

    All Science Journal Classification (ASJC) codes

    • Physical and Theoretical Chemistry
    • Inorganic Chemistry
    • Materials Chemistry

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