Zinc complex of N-confused calix[4]phyrin

Hiroyuki Furuta, Tomoya Ishizuka, Atsuhiro Osuka

Research output: Contribution to journalArticlepeer-review

26 Citations (Scopus)

Abstract

A zinc(II) complex of N-confused calix[4]phyrin (isoporphyrin) (2-Zn) has been synthesized and the structure was revealed by 1H NMR and X-ray analyses. The atomic distance between zinc metal and the inner-core carbon was about 0.2 Å longer compared with that of zinc(II) N-confused porphyrin complexes, suggesting the weaker side-on η1-coordination with the inner-core-carbon in 2-Zn.

Original languageEnglish
Pages (from-to)398-401
Number of pages4
JournalInorganic Chemistry Communications
Volume6
Issue number4
DOIs
Publication statusPublished - Apr 1 2003

All Science Journal Classification (ASJC) codes

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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