β-1,3-Glucan (Schyzophyllan) can act as a one-dimensional host for creating chirally twisted poly(p-phenylene ethynylene)

Munenori Numata, Tomohisa Fujisawa, Chun Li, Shunichi Haraguchi, Masato Ikeda, Kazuo Sakurai, Seiji Shinkai

研究成果: Contribution to journalArticle

21 引用 (Scopus)

抜粋

It has been demonstrated that a chiral, insulated poly(p-phenylene ethynylene) (PPE) nano-wire can be created by a polymer wrapping method utilizing natural -1,3-glucan polysaccharide schizophyllan (SPG). Spectroscopic and microscopic measurements have revealed that PPE adopts a rigid conformation and exists as one piece in the helical hollow constructed by two SPG chains. Moreover, the inherent helical structure of SPG can induce the chiral twisting of the insulated PPE backbone. It is believed that the present system is really applicable for designing novel chiral sensors based on PPE.

元の言語英語
ページ(範囲)107-113
ページ数7
ジャーナルSupramolecular Chemistry
19
発行部数1-2
DOI
出版物ステータス出版済み - 1 1 2007

All Science Journal Classification (ASJC) codes

  • Chemistry(all)

フィンガープリント β-1,3-Glucan (Schyzophyllan) can act as a one-dimensional host for creating chirally twisted poly(p-phenylene ethynylene)' の研究トピックを掘り下げます。これらはともに一意のフィンガープリントを構成します。

  • これを引用