TY - JOUR
T1 - β-functionalization of 5, 15-diazaporphyrins with phosphorus, oxygen, and sulfur-containing substituents
AU - Sugai, Takuma
AU - Minoura, Mao
AU - Nakano, Haruyuki
AU - Matano, Yoshihiro
N1 - Funding Information:
This work was supported by JSPS KAKENHI (Grant Number: 18H01961 to YM).
PY - 2018
Y1 - 2018
N2 - The β-functionalization of 5, 15-diazaporphyrins (DAPs) with phosphoryl, phenoxy, sulfanyl, and sulfonyl groups was achieved by either cross-coupling or aromatic nucleophilic substitution reactions of β-bromo- and β, β′-dibromo-DAPs. The heteroatom-containing functional groups at the β- positions strongly affected the redox properties of the DAP π-systems.
AB - The β-functionalization of 5, 15-diazaporphyrins (DAPs) with phosphoryl, phenoxy, sulfanyl, and sulfonyl groups was achieved by either cross-coupling or aromatic nucleophilic substitution reactions of β-bromo- and β, β′-dibromo-DAPs. The heteroatom-containing functional groups at the β- positions strongly affected the redox properties of the DAP π-systems.
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U2 - 10.1246/bcsj.20180123
DO - 10.1246/bcsj.20180123
M3 - Article
AN - SCOPUS:85051766222
SN - 0009-2673
VL - 91
SP - 1264
EP - 1266
JO - Bulletin of the Chemical Society of Japan
JF - Bulletin of the Chemical Society of Japan
IS - 8
ER -