γ-silyl group effect in hydroalumination and carbolithiation of propargylic alcohols

研究成果: Contribution to journalArticle査読

25 被引用数 (Scopus)

抄録

(Chemical Equation Presented) Making the right substitution: A remarkable acceleration effect of phenyl-substituted silyl groups in hydroalumination and carbolithiation reactions of propargylic alcohols (see formula) is described. The results show that an aryl silyl group can act not only as a protecting group but also as an activating group of the alkynyl moiety. This work provides an efficient group-selective approach to multifunctionalized alkenes.

本文言語英語
ページ(範囲)232-234
ページ数3
ジャーナルAngewandte Chemie - International Edition
45
2
DOI
出版ステータス出版済み - 12 23 2005
外部発表はい

All Science Journal Classification (ASJC) codes

  • 触媒
  • 化学 (全般)

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