(η6-arene)RuII/chiral SN ligand: A novel bifunctional catalyst system for asymmetric transfer hydrogenation of aromatic ketones

Masato Ito, Yuji Shibata, Akira Watanabe, Takao Ikariya

研究成果: Contribution to journalArticle査読

25 被引用数 (Scopus)

抄録

A binary catalyst system of [RuCl26-arene)] 2 and a protic aminothiol (SN) ligand has been found to promote hydrogen transfer between alcohols and carbonyl compounds. The chiral catalyst system with the pipecolinol-derived chiral SN ligand displays excellent stereoselectivity in the asymmetric transfer hydrogenation of aromatic ketones using HCO2H-Et3N. Novel unsymmetrical bis(thiolate)- bridged binuclear complex, which is relevant to the generation of catalytically active species, has been synthesized and structurally characterized.

本文言語英語
ページ(範囲)1621-1626
ページ数6
ジャーナルSynlett
10
DOI
出版ステータス出版済み - 6 1 2009
外部発表はい

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

フィンガープリント 「(η6-arene)Ru<sup>II</sup>/chiral SN ligand: A novel bifunctional catalyst system for asymmetric transfer hydrogenation of aromatic ketones」の研究トピックを掘り下げます。これらがまとまってユニークなフィンガープリントを構成します。

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