(η6-arene)RuII/chiral SN ligand: A novel bifunctional catalyst system for asymmetric transfer hydrogenation of aromatic ketones

Masato Ito, Yuji Shibata, Akira Watanabe, Takao Ikariya

研究成果: ジャーナルへの寄稿記事

23 引用 (Scopus)

抜粋

A binary catalyst system of [RuCl26-arene)] 2 and a protic aminothiol (SN) ligand has been found to promote hydrogen transfer between alcohols and carbonyl compounds. The chiral catalyst system with the pipecolinol-derived chiral SN ligand displays excellent stereoselectivity in the asymmetric transfer hydrogenation of aromatic ketones using HCO2H-Et3N. Novel unsymmetrical bis(thiolate)- bridged binuclear complex, which is relevant to the generation of catalytically active species, has been synthesized and structurally characterized.

元の言語英語
ページ(範囲)1621-1626
ページ数6
ジャーナルSynlett
発行部数10
DOI
出版物ステータス出版済み - 6 1 2009
外部発表Yes

    フィンガープリント

All Science Journal Classification (ASJC) codes

  • Organic Chemistry

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